V. C. Gibson, E. L. Marshall, D. Navarro-Llobet, Andrew J. P. White, D. Williams
{"title":"一种定义明确的用于丙交酯受控聚合的醇化铁引发剂","authors":"V. C. Gibson, E. L. Marshall, D. Navarro-Llobet, Andrew J. P. White, D. Williams","doi":"10.1039/B209703F","DOIUrl":null,"url":null,"abstract":"The three-coordinate iron(II) complex, (But-BDI)FeOBut \n[But-BDI = HC(C(But)N-2,6-iPr2C6H3)2] is found to be a highly active initiator for the polymerisation of lactide and caprolactone at room temperature.","PeriodicalId":17317,"journal":{"name":"Journal of The Chemical Society-dalton Transactions","volume":"13 1","pages":"4321-4322"},"PeriodicalIF":0.0000,"publicationDate":"2002-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"84","resultStr":"{\"title\":\"A well-defined iron(II) alkoxide initiator for the controlled polymerisation of lactide\",\"authors\":\"V. C. Gibson, E. L. Marshall, D. Navarro-Llobet, Andrew J. P. White, D. Williams\",\"doi\":\"10.1039/B209703F\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The three-coordinate iron(II) complex, (But-BDI)FeOBut \\n[But-BDI = HC(C(But)N-2,6-iPr2C6H3)2] is found to be a highly active initiator for the polymerisation of lactide and caprolactone at room temperature.\",\"PeriodicalId\":17317,\"journal\":{\"name\":\"Journal of The Chemical Society-dalton Transactions\",\"volume\":\"13 1\",\"pages\":\"4321-4322\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-11-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"84\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society-dalton Transactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/B209703F\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society-dalton Transactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/B209703F","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 84
摘要
三配位铁(II)配合物(But- bdi)FeOBut [But- bdi = HC(C(But) n -2,6- ipr2c6h3)2]是室温下丙交酯和己内酯聚合的高活性引发剂。
A well-defined iron(II) alkoxide initiator for the controlled polymerisation of lactide
The three-coordinate iron(II) complex, (But-BDI)FeOBut
[But-BDI = HC(C(But)N-2,6-iPr2C6H3)2] is found to be a highly active initiator for the polymerisation of lactide and caprolactone at room temperature.