环氧/二硫化钼纳米复合材料的初期放电活性研究

P. Nagachandrika, K. Sridharan, R. Sarathi, N. Yoshimura
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引用次数: 1

摘要

环氧树脂基本上是一种高性能材料,由于其高的电气、热学和机械性能,它被用作所有高压电力设备的绝缘材料。随着纳米材料的进步,其作为填料为实现所需的电学、热学和力学性能提供了更大的优势[1,2]。碳纳米管(CNT)和石墨烯作为电场分级材料[3]具有良好的应用前景。近年来,二硫化钼材料因其固有的高带隙而不影响电导率的特性而越来越受到人们的欢迎,世界各地的研究表明,添加二硫化钼作为填料可以提高材料[4]的机械性能和热性能。在电力设备中,表面放电活动是固体绝缘失效的机制之一。材料的表面电阻率和疏水性对绝缘材料的使用寿命有重要影响。表面电荷的积累可以增强切向电场,导致材料表面放电活性和疏水性变差,从而导致水滴变薄,在水滴边缘附近开始电晕活动。绝缘材料降解的特性变化是由于局部电场的增强而发生的,因此确保绝缘材料表面不受电荷积累/电场增强的影响变得非常重要。传统上,无机填料即碳化硅材料作为环氧树脂的填充材料,由于其半导体性质,可以减轻积累的电荷。近年来,二硫化钼材料因其固有的材料特性和半导电特性而日益受到人们的重视。在正常工作条件下,绝缘材料可能由于表面放电而暴露于放电或由于电晕活动而使绝缘材料降解。这些放电反过来又会导致绝缘材料在一段时间内的降解,从而改变绝缘材料的基本特性,从而降低设备[6]的寿命。因此,迫切需要开发具有良好耐放电特性的电绝缘材料。最近,CIGRE工作组已经表示要开发非标准材料以提高性能。碳化硅增强环氧树脂具有良好的抗局部放电特性。在电力领域,它通常被用作高压电机的应力分级物质[9,10]。许多研究报道了在正常环境温度下运行的电力设备中使用非线性介电体。绝缘材料的一个主要问题是水汽凝结形成水滴。在高电场作用下,当绝缘材料顶部有一个水滴时,电晕活动开始,表面放电活动随之开始,导致表面温度升高,从而导致环氧/二硫化钼纳米复合材料的初始放电活性
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Understanding the Incipient Discharge Activity with Epoxy/MoS2 Nanocomposites
Epoxy resin is basically a high-performance material and is used as an insulant in all high voltage power apparatus because of its high electrical, thermal and mechanical properties. With the advancement of nano materials, its use as filler has provided greater advantage to achieve required electrical, thermal and mechanical properties [1, 2]. Carbon nanotubes (CNT) and graphene have good application to use as an electric fi eld grading material [3]. Recently, MoS2 material is gaining popularity because of its inherent characteristics of high band gap which will not impart electrical conductivity and the world over researchers have indicated that addition of it as filler content can enhance mechanical and thermal properties of the material [4]. In power apparatus, surface discharge activity is one of the mechanisms by which the solid insulation fails. The surface resistivity and hydrophobicity of the material play an important role on life of insulating material. The surface charge accumulation can enhance the tangential electric field, leading to surface discharge activity and poor hydrophobicity of the material, which lead to thinning of water droplet causing inception of corona activity near the water droplet edge. The characteristic variation in degradation of insulating material occurs due to enhancement of local electric fi eld and hence it has become important to ensure the surface free from charge accumulation/electric field enhancement in the insulating material. Conventionally, the inorganic fillers, namely, silicon carbide material is used as a fi ller material in epoxy resin, which can relieve the accumulated charge, because of its semiconducting properties. In recent times, the molybdenum di-sulphide material, is gaining importance because of its inherent material properties and can be alternative material because of its semi-conductive nature [5]. Under normal operating conditions, the insulating material may expose to electrical discharges due to surface discharges or degradation of insulating materials due to corona activity. These discharges in turn can cause degradation of the insulating material over a period thereby alternating the fundamental properties of insulating material thereby reducing the life of the equipment [6]. Therefore, there is a strong need for developing electrical insulating materials possessing good discharge resistant characteristics. Recently, CIGRE working group has indicated development of non-standard materials for improved performance [7]. Epoxy resin with silicon carbide reinforcement exhibits good partial discharge resistance characteristics [8]. In the electric power sector, it is generally utilized as stress grading substance for high voltage electrical machines [9, 10]. Many studies have reported the use of non-linear dielectrics in power apparatus operating at normal ambient temperatures [11]. A major problem with insulating material is moisture condensation forming water droplet. If a water droplet is sitting on the top of insulating material, under high electric field, corona activity incepts followed with surface discharge activity, causing surface temperature rise followed Understanding the Incipient Discharge Activity with Epoxy/MoS2 Nanocomposites
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