{"title":"含有邻硝基硫代取代基的化合物的光解作用","authors":"R. S. Goudie, P. Preston","doi":"10.1039/J39710003081","DOIUrl":null,"url":null,"abstract":"The photolysis of a number of compounds containing an o-nitroarylthio-substituent has been investigated. Decarboxylation occurs in certain carboxylic acid derivatives and the mechanism of these reactions is considered. In contrast to its thermolysis, photolysis of N-(o-nitrophenylthio)aniline provides 4′-anilinoazobenzene-2-sulphinic acid in moderate yield.","PeriodicalId":17245,"journal":{"name":"Journal of The Chemical Society C: Organic","volume":"12 5 1","pages":"3081-3084"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Photolysis of compounds containing an o-nitroarylthio-substituent\",\"authors\":\"R. S. Goudie, P. Preston\",\"doi\":\"10.1039/J39710003081\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The photolysis of a number of compounds containing an o-nitroarylthio-substituent has been investigated. Decarboxylation occurs in certain carboxylic acid derivatives and the mechanism of these reactions is considered. In contrast to its thermolysis, photolysis of N-(o-nitrophenylthio)aniline provides 4′-anilinoazobenzene-2-sulphinic acid in moderate yield.\",\"PeriodicalId\":17245,\"journal\":{\"name\":\"Journal of The Chemical Society C: Organic\",\"volume\":\"12 5 1\",\"pages\":\"3081-3084\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society C: Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J39710003081\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society C: Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J39710003081","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Photolysis of compounds containing an o-nitroarylthio-substituent
The photolysis of a number of compounds containing an o-nitroarylthio-substituent has been investigated. Decarboxylation occurs in certain carboxylic acid derivatives and the mechanism of these reactions is considered. In contrast to its thermolysis, photolysis of N-(o-nitrophenylthio)aniline provides 4′-anilinoazobenzene-2-sulphinic acid in moderate yield.
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