细菌切断乙醚键。

Microbiological reviews Pub Date : 1996-03-01 DOI:10.1128/MMBR.60.1.216-232.1996

G. White, N. Russell, E. C. Tidswell

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引用次数: 173

摘要

介绍216问题污染物和醚裂解217农用化学品217聚醚218聚乙二醇218聚丙烯乙二醇和聚四甲基乙二醇219洗涤剂219助洗剂219醇乙氧基酯219烷基酚乙氧基酯220烷基乙氧基硫酸盐表面活性剂220醚裂解的生化机制221氧化221细胞色素P-450氧化221羟基转移机制223水解225烷基芳基醚厌氧O脱烷基225氧化到羧酸226还原227裂解酶的碳氧键裂解228结束语228知识现状与展望228途径228酶229新兴主题229醚裂解系统的天然底物229确认230参考文献230

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Bacterial scission of ether bonds.

INTRODUCTION 216 PROBLEM POLLUTANTS AND ETHER SCISSION 217 Agrochemicals 217 Polyethers 218 Polyethylene glycols 218 Polypropylene glycols and polytetramethylene glycols 219 Detergents 219 Builder compounds 219 Alcohol ethoxylates 219 Alkylphenol ethoxylates 220 Alkylethoxy sulfate surfactants 220 BIOCHEMICAL MECHANISMS OF ETHER CLEAVAGE 221 Oxygenation 221 Oxidation by Cytochromes P-450 221 Hydroxyl Shift Mechanisms 223 Hydrolysis 225 Anaerobic O Dealkylation of Alkyl-Aryl Ethers 225 Oxidation to Carboxylic Acids 226 Reduction 227 Carbon-Oxygen Bond Cleavage by Lyases 228 CONCLUDING REMARKS 228 State of Knowledge and Prospects 228 Pathways 228 Enzymes 229 Emerging Themes 229 Natural Substrates for Ether Cleavage Systems 229 ACKNOWLEDGMENT 230 REFERENCES 230

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Microbiological reviews

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