晶格相容性理论:记录的I-III-O2三元氧化物陶瓷在低温下与碲化三元和硫化物三元陶瓷不稳定性的争论

IF 18.6 1区材料科学 Q1 MATERIALS SCIENCE, CERAMICS

Journal of Advanced Ceramics Pub Date : 2013-01-02 DOI:10.1155/2013/734015

K. Boubaker

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引用次数: 15

摘要

在最近提出的晶格相容理论(LCT)框架下，研究了黄铜矿三元氧化陶瓷与碲化物和硫化物之间的一些记录行为差异。用乌尔巴赫尾波和原子价壳层电子轨道特征值对变化进行了评价，这些特征值是通过几种近似计算得到的。该研究的目的主要是试图解释在允许三元碲化物和硫化物结晶的条件下，在相对较低的温度下制备黄铜矿三元氧化陶瓷(I-III-O2)的困难问题。

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The Lattice Compatibility Theory: Arguments for Recorded I-III-O2 Ternary Oxide Ceramics Instability at Low Temperatures beside Ternary Telluride and Sulphide Ceramics

Some recorded behaviours differences between chalcopyrite ternary oxide ceramics and telluride and sulphides are investigated in the framework of the recently proposed Lattice Compatibility Theory (LCT). Alterations have been evaluated in terms of Urbach tailing and atomic valence shell electrons orbital eigenvalues, which were calculated through several approximations. The aim of the study was mainly an attempt to explain the intriguing problem of difficulties of elaborating chalcopyrite ternary oxide ceramics (I-III-O2) at relatively low temperatures under conditions which allowed crystallization of ternary telluride and sulphides.

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来源期刊

Journal of Advanced Ceramics MATERIALS SCIENCE, CERAMICS-

CiteScore

21.00

自引率

10.70%

发文量

290

审稿时长

14 days

期刊介绍： Journal of Advanced Ceramics is a single-blind peer-reviewed, open access international journal published on behalf of the State Key Laboratory of New Ceramics and Fine Processing (Tsinghua University, China) and the Advanced Ceramics Division of the Chinese Ceramic Society. Journal of Advanced Ceramics provides a forum for publishing original research papers, rapid communications, and commissioned reviews relating to advanced ceramic materials in the forms of particulates, dense or porous bodies, thin/thick films or coatings and laminated, graded and composite structures.