{"title":"掺锶羟基磷灰石陶瓷的制备及其铁电性能","authors":"Hongquan Zhang","doi":"10.13168/cs.2023.0016","DOIUrl":null,"url":null,"abstract":"Strontium-doped hydroxyapatite ceramics with good ferroelectric properties were prepared using 5 % bioactive phosphate glass as an additive at 700 °C in this paper. XRD, FTIR, SEM analyses and a ferroelectric tester were used to analyse the crystal structure, phase composition, microstructure and ferroelectric properties of the prepared ceramics. The results revealed that substitution of Ca 2+ by Sr 2+ in the HA lattice would lead to an increase in its lattice parameters and a decrease in crystallinity. Moreover, the lattice distortion and the increase in the electric dipole moment caused by the Sr 2+ doping enhanced the ferroelectric properties of the Sr-HA ceramics. Increasing the density of the samples could enhance their ferroelectric properties. The remnant polarisation intensity increased from 0.0156 μC∙cm-2 to 0.0728 μC∙cm-2, the maximum polarisation intensity increased from 0.1210 μC∙cm -2 to 0.1628 μC∙cm -2 .","PeriodicalId":9857,"journal":{"name":"Ceramics-silikaty","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"PREPARATION AND FERROELECTRIC PROPERTIES OF STRONTIUM-DOPED HYDROXYAPATITE CERAMICS\",\"authors\":\"Hongquan Zhang\",\"doi\":\"10.13168/cs.2023.0016\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Strontium-doped hydroxyapatite ceramics with good ferroelectric properties were prepared using 5 % bioactive phosphate glass as an additive at 700 °C in this paper. XRD, FTIR, SEM analyses and a ferroelectric tester were used to analyse the crystal structure, phase composition, microstructure and ferroelectric properties of the prepared ceramics. The results revealed that substitution of Ca 2+ by Sr 2+ in the HA lattice would lead to an increase in its lattice parameters and a decrease in crystallinity. Moreover, the lattice distortion and the increase in the electric dipole moment caused by the Sr 2+ doping enhanced the ferroelectric properties of the Sr-HA ceramics. Increasing the density of the samples could enhance their ferroelectric properties. The remnant polarisation intensity increased from 0.0156 μC∙cm-2 to 0.0728 μC∙cm-2, the maximum polarisation intensity increased from 0.1210 μC∙cm -2 to 0.1628 μC∙cm -2 .\",\"PeriodicalId\":9857,\"journal\":{\"name\":\"Ceramics-silikaty\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2023-04-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics-silikaty\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.13168/cs.2023.0016\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics-silikaty","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.13168/cs.2023.0016","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
PREPARATION AND FERROELECTRIC PROPERTIES OF STRONTIUM-DOPED HYDROXYAPATITE CERAMICS
Strontium-doped hydroxyapatite ceramics with good ferroelectric properties were prepared using 5 % bioactive phosphate glass as an additive at 700 °C in this paper. XRD, FTIR, SEM analyses and a ferroelectric tester were used to analyse the crystal structure, phase composition, microstructure and ferroelectric properties of the prepared ceramics. The results revealed that substitution of Ca 2+ by Sr 2+ in the HA lattice would lead to an increase in its lattice parameters and a decrease in crystallinity. Moreover, the lattice distortion and the increase in the electric dipole moment caused by the Sr 2+ doping enhanced the ferroelectric properties of the Sr-HA ceramics. Increasing the density of the samples could enhance their ferroelectric properties. The remnant polarisation intensity increased from 0.0156 μC∙cm-2 to 0.0728 μC∙cm-2, the maximum polarisation intensity increased from 0.1210 μC∙cm -2 to 0.1628 μC∙cm -2 .
期刊介绍:
The journal Ceramics-Silikáty accepts papers concerned with the following ranges of material science:
Chemistry and physics of ceramics and glasses
Theoretical principles of their engineering including computing methods
Advanced technologies in the production of starting materials, glasses and ceramics
Properties and applications of modern materials
Special analytical procedures
Engineering ceramic including composites
Glass and ceramics for electronics and optoelectronics
High temperature superconducting materials
Materials based on cement or other inorganic binders
Materials for biological application
Advanced inorganic glasses with special properties
Fibrous materials Coatings and films based on inorganic non-metallic materials.