{"title":"4 kPa下水+ 2-叠氮- n, n -二甲基乙胺体系等压汽液平衡数据的测定与相关性","authors":"Hosein Rouhandeh, Iran Tehran, S. Pakdehi","doi":"10.23939/CHCHT15.02.226","DOIUrl":null,"url":null,"abstract":"Isobaric vapor-liquid equilibrium (VLE) data for binary system of water + 2-azido-N,N-dimethylethanamine (DMAZ) was measured at 4 kPa. The results showed an azeotropic point at x1 = 0.985 and T = 302.17 K. The data was correlated with nonrandom two-liquid (NRTL), Wilson and universal quasi-chemical activity coefficient (UNIQUAC) models for the liquid phase. A comparison of the model performances was made using of the criterion of the average absolute deviation, standard deviation and mean standard deviation in boiling-point temperature. The results indicated that the NRTL activity coefficient model satisfactorily correlated the VLE data.","PeriodicalId":9793,"journal":{"name":"Chemistry & Chemical Technology","volume":null,"pages":null},"PeriodicalIF":1.0000,"publicationDate":"2021-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Measurement and Correlation of Isobaric Vapor-Liquid Equilibrium Data for Water + 2-Azido-N,N-Dimethylethanamine System at 4 kPa\",\"authors\":\"Hosein Rouhandeh, Iran Tehran, S. Pakdehi\",\"doi\":\"10.23939/CHCHT15.02.226\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Isobaric vapor-liquid equilibrium (VLE) data for binary system of water + 2-azido-N,N-dimethylethanamine (DMAZ) was measured at 4 kPa. The results showed an azeotropic point at x1 = 0.985 and T = 302.17 K. The data was correlated with nonrandom two-liquid (NRTL), Wilson and universal quasi-chemical activity coefficient (UNIQUAC) models for the liquid phase. A comparison of the model performances was made using of the criterion of the average absolute deviation, standard deviation and mean standard deviation in boiling-point temperature. The results indicated that the NRTL activity coefficient model satisfactorily correlated the VLE data.\",\"PeriodicalId\":9793,\"journal\":{\"name\":\"Chemistry & Chemical Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2021-06-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry & Chemical Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.23939/CHCHT15.02.226\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry & Chemical Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.23939/CHCHT15.02.226","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 1
摘要
测定了水+ 2-叠氮- n, n -二甲基乙胺(DMAZ)二元体系在4 kPa下的等压汽液平衡(VLE)数据。结果表明，共沸点x1 = 0.985, T = 302.17 K。数据与液相的非随机双液(NRTL)、Wilson和通用准化学活度系数(UNIQUAC)模型相关。以沸点温度的平均绝对偏差、标准偏差和平均标准偏差为准则，对模型的性能进行了比较。结果表明，NRTL活度系数模型与VLE数据的相关性较好。
Measurement and Correlation of Isobaric Vapor-Liquid Equilibrium Data for Water + 2-Azido-N,N-Dimethylethanamine System at 4 kPa
Isobaric vapor-liquid equilibrium (VLE) data for binary system of water + 2-azido-N,N-dimethylethanamine (DMAZ) was measured at 4 kPa. The results showed an azeotropic point at x1 = 0.985 and T = 302.17 K. The data was correlated with nonrandom two-liquid (NRTL), Wilson and universal quasi-chemical activity coefficient (UNIQUAC) models for the liquid phase. A comparison of the model performances was made using of the criterion of the average absolute deviation, standard deviation and mean standard deviation in boiling-point temperature. The results indicated that the NRTL activity coefficient model satisfactorily correlated the VLE data.
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