钪离子与CNP - lf (h +) - ab-17-8 (oh -)体系相互作用的特点

Khuangul Khimersen, Т. Jumadilov, Zh.S. Mukatayeva, Zh.K. Korganbayeva, J. Haponiuk, A. Imangazy
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引用次数: 0

摘要

研究了基于lewait CNP LF和AB-17-8工业离子交换的聚合物间体系对钪离子的吸附关系。本研究的目的是研究lewait CNP LF:AV-17-8聚合物间体系对钪离子的吸附能力。方法。在Jenway-6305分光光度计上测量了溶液的光密度,计算了吸收参数。结果表明:当聚合物的摩尔比为3:3、2:4和1:5时,“lewait CNP LF:AV-17-8”共聚物体系在相互作用48 h内的最大吸附度为26.4%;分别为27.9%和26%。可以看出,当比例为2:4时,吸附度值最大。与单独离子交换剂lewait CNP LF(6:0)和AV-17-8(0:6)的吸附度相比,该比例的吸附度值分别提高了32.5%和28.5%。在lewait CNP LF:AV-17-8共聚物体系中,当比例为3:3时,聚合物与钪离子在48 h后的链结合度最高;2:4和1:5分别为4.87%、5.25%和5.01%。lewait CNPLF(6:0)和AV-17-8(0:6)离子交换剂在48 h后的聚合物链结合度分别为3.68%和4.26%。结论。结果表明,离子交换树脂与聚合物间体系的相互活化导致其吸附能力显著提高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
FEATURES OF THE SCANDIUM IONS INTERACTION WITH THE INTERPOLYMER SYSTEM LEWATIT CNP LF (H+ ) - AB-17-8 (OH- ) SYSTEM
The sorption of the interpolymer systems on the basis on Lewatit CNP LF and AB-17-8 industrial ion exchanges in the relation to scandium ions has been studied. The purpose of this research has been to study the sorption capacity of the interpolymer system “Lewatit CNP LF:AV-17-8” in relation to scandium ions. Methodology. To calculate the sorption parameters, the optical density of the solutions has been measured on the Jenway-6305 spectrophotometer. The obtained results have shown that the maximum sorption degree of the “Lewatit CNP LF:AV-17-8” interpolymer systems during 48 h of interaction has occurred in the molar ratios (3:3, 2:4 and 1:5) of polymers, the sorption degrees have been 26.4%; 27.9% and 26%, respectively. As can be seen, the value of the sorption degree is maximum at the ratio of 2:4. The value of the sorption degree in this ratio is higher by 32.5% and 28.5%, respectively, as compared with the degree of sorption of individual ion exchangers Lewatit CNP LF (6:0) and AV-17-8 (0:6).The highest values of the polymer chain binding degree after 48 h with scandium ions in the interpolymer system “Lewatit CNP LF:AV-17-8” for the ratios of 3:3; 2:4 and 1:5 have been 4.87%, 5.25% and 5.01%, respectively. The values of the polymer chain binding degree of the individual Lewatit CNPLF (6:0) and AV-17-8 (0:6) ion exchangers, after 48 h have been 3.68% and 4.26%, respectively. Conclusion. The obtained results have shown that the mutual activation of ion exchange resin the interpolymer system leads to a significant increase in their sorption capacity.
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