六氯锑酸烷氧磷的核磁共振研究

Journal of The Chemical Society B: Physical Organic Pub Date : 1971-01-01 DOI:10.1039/J29710001714

M. Murray, R. Schmutzler, E. Gründemann, H. Teichmann

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引用次数: 12

摘要

给出了一系列六氯锑酸烷氧磷的1h和31P核磁共振数据，并与相应的磷基化合物的类似数据进行了比较。31P化学位移不能用Letcher和Van Wazer的理论处理来解释，并提出了替代的经验相关性。

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Nuclear magnetic resonance studies of alkoxyphosphonium hexachloroantimonates

1 H and 31P N.m.r. data of a series of alkoxyphosphonium hexachloroantimonates are presented and compared with similar data for the corresponding phosphoryl compounds. The 31P chemical shifts cannot be explained by the theoretical treatment of Letcher and Van Wazer, and alternative empirical correlations are suggested.

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Journal of The Chemical Society B: Physical Organic

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