{"title":"用时间分辨x射线吸收光谱原位观察导电聚合物中铜和铁的电化学包合","authors":"D. Guay, G. Tourillon, A. Fontaine","doi":"10.1039/DC9908900041","DOIUrl":null,"url":null,"abstract":"A comparative in situ time-resolved X-ray absorption study of the electrochemical inclusion of copper and iron species in poly(3-methyl-thiophene)(PMeT) is reported. For both treatments, incorporation of metallic ion and complexation with sulphur atoms of the polymer backbone lead to a significant increase of the ex situ macroscopic conductivity. However, the detailed mechanisms and kinetics of the various processes are specific to the metallic ion incorporated in the polymer.","PeriodicalId":12210,"journal":{"name":"Faraday Discussions of The Chemical Society","volume":"21 1","pages":"41-50"},"PeriodicalIF":0.0000,"publicationDate":"1990-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":"{\"title\":\"Electrochemical inclusion of copper and iron species in a conducting polymer observed in situ using time-resolved X-ray absorption spectroscopy\",\"authors\":\"D. Guay, G. Tourillon, A. Fontaine\",\"doi\":\"10.1039/DC9908900041\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A comparative in situ time-resolved X-ray absorption study of the electrochemical inclusion of copper and iron species in poly(3-methyl-thiophene)(PMeT) is reported. For both treatments, incorporation of metallic ion and complexation with sulphur atoms of the polymer backbone lead to a significant increase of the ex situ macroscopic conductivity. However, the detailed mechanisms and kinetics of the various processes are specific to the metallic ion incorporated in the polymer.\",\"PeriodicalId\":12210,\"journal\":{\"name\":\"Faraday Discussions of The Chemical Society\",\"volume\":\"21 1\",\"pages\":\"41-50\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1990-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"9\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Faraday Discussions of The Chemical Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/DC9908900041\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Faraday Discussions of The Chemical Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/DC9908900041","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Electrochemical inclusion of copper and iron species in a conducting polymer observed in situ using time-resolved X-ray absorption spectroscopy
A comparative in situ time-resolved X-ray absorption study of the electrochemical inclusion of copper and iron species in poly(3-methyl-thiophene)(PMeT) is reported. For both treatments, incorporation of metallic ion and complexation with sulphur atoms of the polymer backbone lead to a significant increase of the ex situ macroscopic conductivity. However, the detailed mechanisms and kinetics of the various processes are specific to the metallic ion incorporated in the polymer.
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