比较化学的练习——论替代当今生物化学世界的可能性

D. Iga
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引用次数: 0

摘要

最多有四种类型(组)的异构体已经被发现,在自然事物或设想的结构:中位体,C2对称,不对称,结构。在脊椎动物中几乎只发现了构象异构体。另一方面,所有基本的自然组合,如在脊椎动物中发现的构成异构体,都能够形成对称的异构体。(因此,他们认为对称是一种可能性,而不是现实)。构式异构体的对称异构体也具有官能团。因此,可以将真实的情况与可能的情况进行比较,并从这种比较中得出有趣而独特的结论。一系列对称的化合物,特别是C2对称的化合物,已经从植物和微生物中分离出来,但是在脊椎动物中没有发现这些组合的对应物。然而,可以得出一个初步的结论:对称现象在植物和微生物中比在脊椎动物中表现得更好。对于对称异构体,介观异构体的特征是对称的镜像面,即能够隐藏(掩盖)原子或偏振光的平面结构的区域。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
An Exercise of Comparative Chemistry – On the Possibility of an Alternative to the Chemical World of Today Living Things
At most four types (groups) of isomers have been revealed, in natural things or as envisaged structures: meso, C2 symmetrical, irrechi, constitutional. In vertebrate almost exclusively constitutional isomers have been found. On the other hand, all fundamental natural combinations, found as constitutional isomers in vertebrates, are able to form symmetric isomers. (Hence, they keep symmetry as a possibility and not as a reality). Symmetric isomers of constitutional ones also possess functional groups. Therefore, a comparison could be made between a real and a possible situation, and an interesting and unique conclusion results from this comparison. A series of symmetric compounds, especially C2 symmetrical ones, have been isolated from plants and microorganisms, however no counterparts of these combinations were ever found in vertebrates. However, a preliminary conclusion could be drawn: symmetry phenomenon is much better represented in plants and microorganisms than in vertebrates. Of symmetric isomers, the meso ones are characterized by a mirror plane of symmetry, i.e. an area capable to hide (mask) atoms or planar structures of polarized light.
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