粉煤灰磁性吸附剂去除水溶液中的镉离子

G. Buema, N. Lupu, H. Chiriac, D. Herea, L. Favier, G. Ciobanu, Loredana Forminte, M. Harja
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引用次数: 3

摘要

本研究以罗马尼亚某电厂产生的粉煤灰为起始材料。本研究的目的是在用Fe3O4处理粉煤灰的基础上,获得一种低成本的材料,作为去除镉离子的吸附剂。采用不同的工艺对所合成的吸附剂进行了表征。在室温条件下,采用间歇式吸附技术对吸附过程进行了研究。用分光光度法测定了镉离子的吸附量。实验数据表明,该材料在三种工作浓度下均能去除镉离子。吸附量随浓度的增加而增加,分别随接触时间的增加而增加。通过拟一阶和拟二阶动力学模型对结果进行了分析。磁性材料对镉的最大吸附量分别为4.03 mg/g、6.73 mg/g和9.65 mg/g,吸附动力学结果与拟二级模型吻合较好。此外,将伪二阶模型线性化为四种类型。结果表明,所制备的材料具有从水溶液中去除镉离子的能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
FLY ASH MAGNETIC ADSORBENT FOR CADMIUM ION REMOVAL FROM AN AQUEOUS SOLUTION
The fly ash generated from a Romanian power plant was used as a starting material in this study. The aim of the study was to obtain a low cost material based on the treatment of fly ash with Fe3O4 for utilization as an adsorbent for cadmium ion removal. The adsorbent that was synthesized was characterized using different techniques. The adsorption process was investigated by the batch technique at room temperature. The quantity of cadmium ion adsorbed was measured spectrophotometrically. The experimental data showed that the material can remove cadmium ions at all three working concentrations. The adsorption capacity increased with an increase in concentration, respectively contact time. The results were analyzed through two kinetic models: pseudo first order and pseudo second order. The kinetics results of cadmium adsorption onto a magnetic material are in good agreement with a pseudo second order model, with a maximum adsorption capacity of 4.03 mg/g, 6.73 mg/g, and 9.65 mg/g. Additionally, the pseudo second order model was linearized into its four types. The results indicated that the material obtained show the ability to remove cadmium ions from an aqueous solution.
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