磁性藻酸盐珠饰煤飞灰合成沸石:在砷钒解毒中的应用

Q4 Earth and Planetary Sciences
Mineralogia Pub Date : 2023-01-01 DOI:10.2478/mipo-2023-0003
Eugeniusz Swistun, Maciej Sobczyk, A. S. K. Kumar, W. Tseng, T. Bajda
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引用次数: 0

摘要

重金属毒性是污染物治理的高要求和具有挑战性的问题。为了解决上述问题,我们提出了水热合成沸石(NaX-UP)的方法。通过聚乙亚胺(PEI)的进一步表面修饰可以得到胺修饰的沸石纳米片(NSs),其表面具有大量的羟基和氨基(Al-O, Si-O-Si, Si-OH和NH2),表面装饰有磁性纳米颗粒(Fe3O4 NPs),能够与分子间和分子内氢键桥接,另外静电相互作用可能是一个重要的作用。此外,这可以转化为磁珠交联与海藻酸钠浸泡在过量的氯化钙溶液。As形成的Fe3O4 NPs修饰的胺修饰的海藻酸沸石微球记为(Fe3O4 NPs修饰的@ pei - NSs海藻酸沸石微球)具有明显的优势,其目的是清除水溶液中的阴离子污染物[As(V) & V(V)]。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthetic zeolite derived from coal fly ash decorated with magnetic alginate bead: Application to detoxification of arsenic and vanadium
Abstract Heavy metal toxicity is highly demanding and challenging to clean up the pollutants. To recover the issues mentioned above, we propose a hydrothermal synthesis of zeolite (NaX-UP). Further surface modification by poly-ethylenimine (PEI) could turn to be amine-modified zeolite nanosheets (zeolite NSs) possessed plenty of hydroxyl and amino groups (Al-O, Si-O-Si, Si-OH and NH2) on their surface, decorated with magnetic nanoparticles (Fe3O4 NPs), that are enabled to bridge with inter and intramolecular hydrogen bonding an additionally electrostatic interaction might be a significant role. Further, this can be converted into magnetic bead crosslinking with sodium alginate immersed in an excess calcium chloride solution. The-as formed Fe3O4 NPs decorated amine modified zeolite alginate bead denoted to be (Fe3O4 NPs decorated @PEI-zeolite NSs alginate bead) upholding a significant advantage would aim to clean up the anionic pollutants are [As(V) & V(V)] from an aqueous solution.
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来源期刊
Mineralogia
Mineralogia Earth and Planetary Sciences-Geology
CiteScore
0.80
自引率
0.00%
发文量
5
期刊介绍: - original papers in the scope of widely understood mineralogical sciences (mineralogy, petrology, geochemistry, environmental sciences, applied mineralogy etc.) - research articles, short communications, mini-reviews and review articles
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