马尾草中CaO催化剂的合成、表征及其在生物柴油生产中的应用

O. Amusan, H. Louis, Adejoke T. Hamzat, Amusan Oluwatobi Omotola, O. Oyebanji, Ayodeji T. Alagbe, T. Magu
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引用次数: 0

摘要

在本研究中,以Achatina achatinshell为原料来源,生产氧化钙作为催化剂用于生产生物柴油。本研究的主要目的是研究不同温度对马尾松煅烧过程中形成的氧化钙的影响,以研究其在生物柴油生产中作为多相催化剂的可能性。首先对壳进行研磨,然后在0°C至1000°C的不同温度下进行煅烧。经煅烧后,A. achatinina壳中的CaCO3转化为氧化钙。用傅里叶变换红外光谱(FT-IR)对所得氧化钙进行了表征。在CO32-(cm-1)的平面振动模式上观察到,CO32-(cm-1)吸收的不对称拉伸与温度的升高不成正比。在100°C和800°C时,o - h拉伸带(cm-1)的吸收值相似。Pearson相关分析表明,吸收率与温度呈正、负相关关系,在pA处差异显著。由于其易得性好、对环境无不良影响,是生产生物柴油的理想催化剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and characterization of CaO catalyst obtained from achatina achatina and its application in biodiesel production
In this research study, Achatina achatinashells was used as the source of raw material to produce calcium oxide which was used as a catalyst in the production of biodiesel. The main aim of this study was to investigate the effect of varying temperatures on the calcium oxide formed using A.  achatina during the calcination process for their possible use as a heterogeneous catalyst in the production of biodiesel. The shells were first grinded and then calcinated at different temperatures ranging from 0 °C to 1000 °C. After calcination, the CaCO3 present in the A. achatinashell was converted to calcium oxide. The obtained calcium oxide was characterized using Fourier transform infrared spectroscopy (FT-IR).  The asymmetric stretching of the CO32- (cm-1) absorption was not proportional with the increasing temperature as it was observed over the plane vibrational modes of CO32-(cm-1). Also, the O-Hstretching band (cm-1) at 100 °C and 800 °C had similar absorption values. Pearson correlation revealed both negative and positive relationship between the absorption rate and the temperature, disclosed a significant difference at pA. achatina shell is a suitable catalyst in the production of Biodiesel because it is readily available and has no adverse effect on the environment.
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