S. Shibutani, S. Yamauchi, Kazuko Kirikoshi, M. Yatagai
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引用次数: 1
摘要
木质材料的热解液体是一种宝贵的森林资源,尽管它们是木炭生产的副产品。研究了热解液的化学除臭效果,以扩大其应用范围。三种由黑栎制成的热解液体。通过除臭试验对栎(Quercus crispula Blume)、栎(Quercus phillyraeoides A. Gray)和毛竹(Phyllostachys pubescens Mazel)进行了评价。五种化合物,氨,三甲胺,硫化氢,甲基硫醇和乙醛,被认为是恶臭的来源。所有热解液对碱性化合物氨和三甲胺均有显著的除臭效果。奈良和mosochiku的热解液对硫化氢和甲基硫醇没有或只有很少的除臭效果,而用ubamegashi的热解液进行24小时的除臭试验,这两种硫化物都减少了30%左右。已经澄清的是,相当数量的乙醛从所有热解液体中挥发出来。
Chemical Deodorant Effects of Pyroligneous Liquids from Woody Materials
Pyroligneous liquids from woody materials are a valuable forest resource, although they are a byproduct of charcoal production. Chemical deodorant effects of pyroligneous liquids were investigated to expand their applications. Three pyroligneous liquids, which were made from nara (Quercus serrata Thunb. and/or Quercus crispula Blume), ubamegashi (Quercus phillyraeoides A. Gray) and mosochiku (Phyllostachys pubescens Mazel), were evaluated through deodorization tests. Five chemical compounds, ammonia, trimethylamine, hydrogen sulfide, methyl mercaptan and acetaldehyde, were adopted as sources of offensive odors. All the pyroligneous liquids showed remarkable deodorant effects on ammonia and trimethylamine, which are basic compounds. Pyroligneous liquids from nara and mosochiku had no or few deodorant effects on hydrogen sulfide and methyl mercaptan, while both the sulfur compounds showed a reduction of about 30% through a 24-hour deodorization test using pyroligneous liquid from ubamegashi. It has been clarified that considerable amounts of acetaldehyde were volatilized from all the pyroligneous liquids.