A. Kennedy, R. Mulvey, C. Raston, B. A. Roberts, R. Rowlings
{"title":"逆冠醚配合物:通过合成[{[(Me3Si)(2)N](4)K2Mg2(O-2)}(无限)]扩展到钾，这是一个以过氧为中心的大环，通过分子间K中心点中心点中心点CH3(SiMe2)相互作用连接成无限链","authors":"A. Kennedy, R. Mulvey, C. Raston, B. A. Roberts, R. Rowlings","doi":"10.1039/a809681c","DOIUrl":null,"url":null,"abstract":"The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.","PeriodicalId":9713,"journal":{"name":"Chemical Communications (london)","volume":"285 1","pages":"353-354"},"PeriodicalIF":0.0000,"publicationDate":"1999-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"38","resultStr":"{\"title\":\"Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac\",\"authors\":\"A. Kennedy, R. Mulvey, C. Raston, B. A. Roberts, R. Rowlings\",\"doi\":\"10.1039/a809681c\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.\",\"PeriodicalId\":9713,\"journal\":{\"name\":\"Chemical Communications (london)\",\"volume\":\"285 1\",\"pages\":\"353-354\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1999-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"38\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications (london)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/a809681c\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications (london)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/a809681c","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac
The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.
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