{"title":"双-苯并咪唑配体稳定单核和双核铜(II)配合物的合成和性质","authors":"Shivakumaraiah, N. Gowda","doi":"10.1081/SIM-200030171","DOIUrl":null,"url":null,"abstract":"Abstract The reactions of copper(II) halides with 1,3‐bis(benzimidazol‐2‐yl)benzene and its N‐methylated derivative afforded binuclear and mononuclear complexes, respectively. Mononuclear perchlorate complexes have also been synthesized by the reactions of the aforesaid ligands with hydrated copper perchlorate. The complexes have been characterized by elemental analyses, conductivity and magnetic measurements, TGA studies, IR, electronic, and ESR spectral studies.","PeriodicalId":22160,"journal":{"name":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2004-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Synthesis and Properties of Mononuclear and Binuclear Copper(II) Complexes Stabilized by bis‐Benzimidazolyl Ligands\",\"authors\":\"Shivakumaraiah, N. Gowda\",\"doi\":\"10.1081/SIM-200030171\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract The reactions of copper(II) halides with 1,3‐bis(benzimidazol‐2‐yl)benzene and its N‐methylated derivative afforded binuclear and mononuclear complexes, respectively. Mononuclear perchlorate complexes have also been synthesized by the reactions of the aforesaid ligands with hydrated copper perchlorate. The complexes have been characterized by elemental analyses, conductivity and magnetic measurements, TGA studies, IR, electronic, and ESR spectral studies.\",\"PeriodicalId\":22160,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/SIM-200030171\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/SIM-200030171","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and Properties of Mononuclear and Binuclear Copper(II) Complexes Stabilized by bis‐Benzimidazolyl Ligands
Abstract The reactions of copper(II) halides with 1,3‐bis(benzimidazol‐2‐yl)benzene and its N‐methylated derivative afforded binuclear and mononuclear complexes, respectively. Mononuclear perchlorate complexes have also been synthesized by the reactions of the aforesaid ligands with hydrated copper perchlorate. The complexes have been characterized by elemental analyses, conductivity and magnetic measurements, TGA studies, IR, electronic, and ESR spectral studies.