{"title":"聚苯乙烯在环烷烃和正烷烃中的相行为比较","authors":"J. Cowie, I. McEwen","doi":"10.1002/PI.4980180608","DOIUrl":null,"url":null,"abstract":"Cloud point curves for several narrow fractions of polystyrene dissolved in cycloheptane, in cyclooctane and in cyclodecane have been established, and the critical solution temperatures extrapolated to give the respective temperatures. All three cycloalkanes are good solvents for the polymer. A comparison is made between the phase behaviour of polystyrene dissolved in cyclic alkanes and in n-alkanes using free volume polymer solution theory.","PeriodicalId":9298,"journal":{"name":"British Polymer Journal","volume":"30 12 1","pages":"387-390"},"PeriodicalIF":0.0000,"publicationDate":"1986-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"A Comparison of the Phase Behaviour of Polystyrene in Cycloalkanes and n‐Alkanes\",\"authors\":\"J. Cowie, I. McEwen\",\"doi\":\"10.1002/PI.4980180608\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Cloud point curves for several narrow fractions of polystyrene dissolved in cycloheptane, in cyclooctane and in cyclodecane have been established, and the critical solution temperatures extrapolated to give the respective temperatures. All three cycloalkanes are good solvents for the polymer. A comparison is made between the phase behaviour of polystyrene dissolved in cyclic alkanes and in n-alkanes using free volume polymer solution theory.\",\"PeriodicalId\":9298,\"journal\":{\"name\":\"British Polymer Journal\",\"volume\":\"30 12 1\",\"pages\":\"387-390\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1986-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"British Polymer Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/PI.4980180608\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"British Polymer Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/PI.4980180608","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A Comparison of the Phase Behaviour of Polystyrene in Cycloalkanes and n‐Alkanes
Cloud point curves for several narrow fractions of polystyrene dissolved in cycloheptane, in cyclooctane and in cyclodecane have been established, and the critical solution temperatures extrapolated to give the respective temperatures. All three cycloalkanes are good solvents for the polymer. A comparison is made between the phase behaviour of polystyrene dissolved in cyclic alkanes and in n-alkanes using free volume polymer solution theory.