聚苯乙烯在环烷烃和正烷烃中的相行为比较

J. Cowie, I. McEwen
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引用次数: 1

摘要

本文建立了聚苯乙烯在环庚烷、环辛烷和环癸烷中溶解的几种窄馏分的云点曲线,并通过临界溶解温度外推得到了相应的温度。这三种环烷烃都是聚合物的良好溶剂。用自由体积聚合物溶液理论比较了聚苯乙烯在环烷烃和正烷烃中的相行为。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Comparison of the Phase Behaviour of Polystyrene in Cycloalkanes and n‐Alkanes
Cloud point curves for several narrow fractions of polystyrene dissolved in cycloheptane, in cyclooctane and in cyclodecane have been established, and the critical solution temperatures extrapolated to give the respective temperatures. All three cycloalkanes are good solvents for the polymer. A comparison is made between the phase behaviour of polystyrene dissolved in cyclic alkanes and in n-alkanes using free volume polymer solution theory.
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