有机晶体的接触电位差与功函数

M. Kotani, H. Akamatu
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引用次数: 24

摘要

采用振动电容法测量了有机晶体的接触电位差。给出了芳烃晶体合理值的功函数。根据功函数,结合其他可观测参数,可以构造出晶体的能量图,表明费米能级的位置与内禀能级的位置略有不同。对紫蒽晶体中由于Dember效应和光伏效应引起的光电动势进行了补充实验,得到了与上述结论一致的结果,表明存在空穴导电。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Contact potential difference and work function of organic crystals
The vibrating condenser method was applied for measurement of the contact potential difference with organic crystals. It gave work functions of reasonable values for aromatic hydrocarbon crystals. From the work function, combined with other observable parameters, an energy diagram for the crystals can be constructed, which indicates that the location of the Fermi level is slightly different from that of the intrinsic level. Supplementary experiments on the photoelectromotive force due to the Dember effect and the photovoltaic effect in violanthrene crystal, gave results consistent with the above conclusion, indicating the hole conduction.
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