二氧化钛及其在机械、电气、光学和生物医学领域的应用

Rajib Das, V. Ambardekar, Partha Pratim Bandyopadhyay
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引用次数: 7

摘要

二氧化钛(TiO2)具有无毒、化学稳定性好、成本低等优点,是最有价值的陶瓷材料之一。TiO2衍生涂层不仅可以作为金属衬底的陶瓷保护层,还可以在紫外线(UV)照射下为金属提供阴极保护,防止腐蚀溶液的腐蚀。二氧化钛涂层具有生物相容性,被广泛用作植入材料。TiO2的酸处理促进了细胞的附着和骨组织与植入物的整合。在本章中,简要讨论了TiO2作为缓蚀剂和生物活性材料的应用。TiO2的半导体性质和高折射率赋予其紫外线屏蔽性能,使其能够吸收或反射紫外线。几项研究表明,通过在防晒霜(保护人体皮肤)和纺织纤维(尽量减少其光化学降解)中加入TiO2,可以实现高紫外线防护系数(UPF)。TiO2的金红石相具有高白度和不透明度,因为它倾向于散射光。这些性质使二氧化钛能够用作颜料,本章也将对其进行简要回顾。由于TiO2具有较高的硬度和断裂韧性,因此TiO2的加入大大降低了复合材料的磨损率。当TiO2在高温下与氢气等气体相互作用时,其电阻会变化到不同的值。利用电阻的变化可以检测各种气体,使得TiO2可以作为气体传感器来监测不同的气体。本章试图全面回顾二氧化钛在机械领域的防腐、耐磨材料、紫外线吸收剂、光学领域的颜料、生物医学领域的生物活性材料以及电领域的气体传感器等方面的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Titanium Dioxide and Its Applications in Mechanical, Electrical, Optical, and Biomedical Fields
Titanium dioxide (TiO2), owing to its non-toxicity, chemical stability, and low cost, is one of the most valuable ceramic materials. TiO2 derived coatings not only act like a ceramic protective shield for the metallic substrate but also provide cathodic protection to the metals against the corrosive solution under Ultraviolet (UV) illumination. Being biocompatible, TiO2 coatings are widely used as an implant material. The acid treatment of TiO2 promotes the attachment of cells and bone tissue integration with the implant. In this chapter, the applications of TiO2 as a corrosion inhibitor and bioactive material are briefly discussed. The semiconducting nature and high refractive index of TiO2 conferred UV shielding properties, allowing it to absorb or reflect UV rays. Several studies showed that a high ultraviolet protection factor (UPF) was achieved by incorporating TiO2 in the sunscreens (to protect the human skin) and textile fibers (to minimize its photochemical degradation). The rutile phase of TiO2 offers high whiteness, and opacity owing to its tendency to scatter light. These properties enable TiO2 to be used as a pigment a brief review of which is also addressed in this chapter. Since TiO2 exhibits high hardness and fracture toughness, the wear rate of composite is considerably reduced by adding TiO2. On interacting with gases like hydrogen at elevated temperatures, the electrical resistance of TiO2 changes to some different value. The change in resistance can be utilized in detecting various gases that enables TiO2 to be used as a gas sensor for monitoring different gases. This chapter attempts to provide a comprehensive review of applications of TiO2 as an anti-corrosion, wear-resistant material in the mechanical field, a UV absorber, pigment in the optical sector, a bioactive material in the biomedical field, and a gas sensor in the electrical domain.
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