Rahmiani Gani, Syarifah Rabiatul Adawiah, Arfiani Nur
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引用次数: 0
摘要
通过改进工作电极,可以优化水电解制氢工艺。采用循环伏安法,以Ag/AgCl为参比电极,Pt为反电极,在不锈钢工作电极上涂覆石墨烯和聚苯胺。采用SEM-EDS和循环伏安法对涂覆电极进行了表征。然后,将合成的电极加入1 ~ 5 g/L的NaHCO3进行水电解。表征数据表明,采用循环伏安法可以合成不锈钢/石墨烯-聚苯胺电极。在-0.2 ~ 0.8 V电压下,以10 mV/s的扫频速率进行10个循环。伏安图表明,在SS/ g - pani5电极上添加2g NaHCO3可获得0.491 mA的最大电解阴极峰电流,在SS/ g - pani5电极上添加2g NaHCO3可获得0.191 mA的最大电解阳极峰电流。根据过电位数据,SS/ g - pani1,0电极获得的H+吸附平均电位差最小,SS/ g - pani1,5电极获得的H+解吸平均电位差最小。关键词:不锈钢,制氢,电镀,电催化剂,电解
Elektroplating Grafena-Polianilina pada Stainless Steel sebagai Elektroda pada Elektrolisis Air untuk Produksi Hidrogen
Hydrogen production by water electrolysis can be optimalized by improve the working electrode. Stainless steel as working electrode was coated with graphene and polyaniline by using cyclic voltammetry method with Ag/AgCl as reference electrode and Pt as counter electrode. Coated electrodes were characterized by SEM-EDS and cyclic voltammetry method. Furthermore, the synthesized electrode was applied for water electrolysis by adding 1- 5 g/L NaHCO3. The characterization data showed that Stainless steel/Graphene-Polyaniline electrode can be synthesized by using cyclic voltammetry. The coating process was conducted at sweeping rate 10 mV/s on voltage -0.2 to 0.8 V for 10 cycles. The voltammograms showed that the highest cathodic peak current of electrolysis obtained at 0.491 mA by addition 2 g NaHCO3 on SS/G-PANi0,5 electrode, and the highest anodic peak current obtained at 0.191 mA by addition 2 g NaHCO3 on SS/G-PANi0,5 electrode. Based on the overpotential data, the smallest average potential difference of H+ adsorption obtained by SS/G-PANi1,0 electrode, and the smallest average potential difference of H+ desorption obtained by SS/G-PANi0,5 electrode.
Keywords: Stainless steel, hydrogen production, electroplating, electrocatalyst, electrolysis