{"title":"六正烯的新合成","authors":"M. Satchell, B. Stacey","doi":"10.1039/J39710000468","DOIUrl":null,"url":null,"abstract":"The reaction of 9,10-dihydroxyanthracene-1,4(2H,3H)-dione with naphthalene-2,3-dicarbaldehyde gives 5,16-dihydroxyhexacene-6,15-quinone (2) in high yield. This compound can be converted into dihydrohexacene, and hence into hexacene, more efficiently than can similar compounds used in earlier syntheses of the polyacene. The use of copper(II) oxide in the dehydrogenation of dihydrohexacene is reported.","PeriodicalId":17245,"journal":{"name":"Journal of The Chemical Society C: Organic","volume":"118 1","pages":"468-469"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"New synthesis of hexacene\",\"authors\":\"M. Satchell, B. Stacey\",\"doi\":\"10.1039/J39710000468\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The reaction of 9,10-dihydroxyanthracene-1,4(2H,3H)-dione with naphthalene-2,3-dicarbaldehyde gives 5,16-dihydroxyhexacene-6,15-quinone (2) in high yield. This compound can be converted into dihydrohexacene, and hence into hexacene, more efficiently than can similar compounds used in earlier syntheses of the polyacene. The use of copper(II) oxide in the dehydrogenation of dihydrohexacene is reported.\",\"PeriodicalId\":17245,\"journal\":{\"name\":\"Journal of The Chemical Society C: Organic\",\"volume\":\"118 1\",\"pages\":\"468-469\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society C: Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J39710000468\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society C: Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J39710000468","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The reaction of 9,10-dihydroxyanthracene-1,4(2H,3H)-dione with naphthalene-2,3-dicarbaldehyde gives 5,16-dihydroxyhexacene-6,15-quinone (2) in high yield. This compound can be converted into dihydrohexacene, and hence into hexacene, more efficiently than can similar compounds used in earlier syntheses of the polyacene. The use of copper(II) oxide in the dehydrogenation of dihydrohexacene is reported.
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