Effects of Post-Harvest Conditions on Sorption Isotherms of Soybeans

Abstract. This study focuses on the modeling of sorption characteristics of three varieties of soybeans (Akras R2, Lono R2, and Podaga R2). Three pretreatments related to post-harvest conditions were tested on the soybean varieties: (1) freshly harvested soybeans, (2) soybeans subjected to three drying and wetting cycles, and (3) soybeans subjected to three freezing and thawing cycles. The adsorption and desorption experiments were conducted at 5°C, 10°C, 15°C, 20°C, 25°C, and 30°C using a dynamic equilibrium relative humidity (ERH) apparatus. Equilibrium moisture content (EMC) and the corresponding ERH were measured. The parameters calculated for the modified Halsey equation are applicable for storage temperatures above 10°C in the relative humidity (RH) ranges of 10% to 80% for desorption and 30% to 80% for adsorption. No significant differences were found in sorption isotherms among the soybean varieties. However, the soybean varieties responded differently to the different pretreatments (i.e., drying/wetting and freezing/thawing cycles). The adsorption isotherms of Akras and Lono soybeans showed significant differences at 10°C to 30°C when subjected to drying and wetting cycles, while Akras and Podaga soybeans showed significant differences in the same temperature range when subjected to freezing and thawing cycles. The effect of drying and wetting cycles on the desorption isotherms was found only for Akras soybeans at 10°C and 15°C below 63% and 71% RH, respectively, and for Lono soybeans at 25°C and 30°C above 69% RH for both temperatures. In general, the effect of both pretreatments on the sorption isotherms of soybeans was a reduction in EMC of up to 20%, when compared to fresh samples at selected storage temperatures. The findings of this study serve as a primary tool for developing a lookup table for safe storage guidelines for soybeans. Keywords: Equilibrium moisture content, Equilibrium relative humidity, Halsey equation, Oswin equation, Soybeans.