{"title":"A novel imprinted electrochemical sensor for dopamine determination based on electron conductivity enhanced by ferrocenyl chalcone derivative film","authors":"Liming Chen","doi":"10.4208/JAMS.100818.112418A","DOIUrl":null,"url":null,"abstract":"A novel biochemical sensor based on molecular imprinted technology was built through electropolymerization. One of the keystones of the technology is the discovery and application of new conductive polymer. Herein, a new conductive ferrocenyl chalcone derivative: [1-Oxo-3-(3-thienyl)-2-propen1-yl] ferrocene (OTPylFc) was synthesized and characterized by nuclear magnetic resonance (NMR) and finally adopted in the technology. The OTPylFc and pyrrole mixture was eletropolymerized in this work and showed satisfying result in improving current peaks. The linear relationship was 1.729× 10 -6 M to 6.916 × 10 -4 M. It is believed that the structure and their conductive analogs formed co-polymers would have a promising prospect in future research.","PeriodicalId":15131,"journal":{"name":"Journal of Atomic and Molecular Sciences","volume":"6 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Atomic and Molecular Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4208/JAMS.100818.112418A","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
摘要
利用电聚合技术构建了一种基于分子印迹技术的新型生化传感器。该技术的关键之一是新型导电聚合物的发现和应用。本文合成了一种新的导电二茂铁基查尔酮衍生物:[1-氧-3-(3-噻吩基)-2-丙烯-基]二茂铁(OTPylFc),并通过核磁共振(NMR)对其进行了表征,最终应用于该技术。本研究将OTPylFc和吡咯混合物电聚合,在改善电流峰方面取得了令人满意的效果。线性关系为1.729× 10 -6 M ~ 6.916 × 10 -4 M,认为该结构及其导电类似物形成的共聚物具有良好的研究前景。
A novel imprinted electrochemical sensor for dopamine determination based on electron conductivity enhanced by ferrocenyl chalcone derivative film
A novel biochemical sensor based on molecular imprinted technology was built through electropolymerization. One of the keystones of the technology is the discovery and application of new conductive polymer. Herein, a new conductive ferrocenyl chalcone derivative: [1-Oxo-3-(3-thienyl)-2-propen1-yl] ferrocene (OTPylFc) was synthesized and characterized by nuclear magnetic resonance (NMR) and finally adopted in the technology. The OTPylFc and pyrrole mixture was eletropolymerized in this work and showed satisfying result in improving current peaks. The linear relationship was 1.729× 10 -6 M to 6.916 × 10 -4 M. It is believed that the structure and their conductive analogs formed co-polymers would have a promising prospect in future research.