多孔镉电极在碱中的阻抗

R.T. Barton, M. Hughes, S.A.G.R. Karunathilaka, P.J. Mitchell, N.A. Hampson
{"title":"多孔镉电极在碱中的阻抗","authors":"R.T. Barton,&nbsp;M. Hughes,&nbsp;S.A.G.R. Karunathilaka,&nbsp;P.J. Mitchell,&nbsp;N.A. Hampson","doi":"10.1016/0376-4583(85)90099-8","DOIUrl":null,"url":null,"abstract":"<div><p>The porous cadmium electrode in alkali has been studied using the impedance technique applied to minielectrodes (area, 1 cm<sup>2</sup>) of conventional sintered structure. It is shown that in a wide frequency domain the electrode behaviour confirms to that of a filmed porous electrode under charge-transfer and diffusion control. In the lower frequency domain the electrode behaviour is more complicated and it is concluded that the frequency response was modified by intruding phase formation effects which were relaxed out at the higher frequencies.</p></div>","PeriodicalId":22037,"journal":{"name":"Surface Technology","volume":"26 4","pages":"Pages 361-367"},"PeriodicalIF":0.0000,"publicationDate":"1985-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0376-4583(85)90099-8","citationCount":"2","resultStr":"{\"title\":\"The impedance of the porous cadmium electrode in alkali\",\"authors\":\"R.T. Barton,&nbsp;M. Hughes,&nbsp;S.A.G.R. Karunathilaka,&nbsp;P.J. Mitchell,&nbsp;N.A. Hampson\",\"doi\":\"10.1016/0376-4583(85)90099-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The porous cadmium electrode in alkali has been studied using the impedance technique applied to minielectrodes (area, 1 cm<sup>2</sup>) of conventional sintered structure. It is shown that in a wide frequency domain the electrode behaviour confirms to that of a filmed porous electrode under charge-transfer and diffusion control. In the lower frequency domain the electrode behaviour is more complicated and it is concluded that the frequency response was modified by intruding phase formation effects which were relaxed out at the higher frequencies.</p></div>\",\"PeriodicalId\":22037,\"journal\":{\"name\":\"Surface Technology\",\"volume\":\"26 4\",\"pages\":\"Pages 361-367\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0376-4583(85)90099-8\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surface Technology\",\"FirstCategoryId\":\"1087\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0376458385900998\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Technology","FirstCategoryId":"1087","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0376458385900998","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2

摘要

采用阻抗技术对传统烧结结构的微电极(面积为1 cm2)在碱介质中的多孔镉电极进行了研究。结果表明,在宽频域中,电极的行为与薄膜多孔电极在电荷转移和扩散控制下的行为一致。在低频域中,电极的行为更为复杂,并得出结论,频率响应被入侵的相形成效应所改变,而这些相形成效应在高频处被放松。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The impedance of the porous cadmium electrode in alkali

The porous cadmium electrode in alkali has been studied using the impedance technique applied to minielectrodes (area, 1 cm2) of conventional sintered structure. It is shown that in a wide frequency domain the electrode behaviour confirms to that of a filmed porous electrode under charge-transfer and diffusion control. In the lower frequency domain the electrode behaviour is more complicated and it is concluded that the frequency response was modified by intruding phase formation effects which were relaxed out at the higher frequencies.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信