{"title":"金属烯醇化物的酸碱和溶剂化性质。第2部分:过渡金属烯醇化物和介质效应","authors":"E. L. Bastos","doi":"10.1002/9780470682531.PAT0937","DOIUrl":null,"url":null,"abstract":"This chapter presents the main aspects of acid–base reactions of transition-metal enolates and an overview of solvent effects on the chemical reactivity of metal enolates. \n \n \nKeywords: \n \nenolate ion; \ntransition-metal enolates; \nmetal Lewis acids; \ndissociation constants; \nsolvent effects; \nacid–base equilibrium","PeriodicalId":20036,"journal":{"name":"Patai's Chemistry of Functional Groups","volume":"16 1","pages":"1-61"},"PeriodicalIF":0.0000,"publicationDate":"2017-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Acid–Base and Solvation Properties of Metal Enolates Part 2: Transition-Metal Enolates and Medium Effects\",\"authors\":\"E. L. Bastos\",\"doi\":\"10.1002/9780470682531.PAT0937\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This chapter presents the main aspects of acid–base reactions of transition-metal enolates and an overview of solvent effects on the chemical reactivity of metal enolates. \\n \\n \\nKeywords: \\n \\nenolate ion; \\ntransition-metal enolates; \\nmetal Lewis acids; \\ndissociation constants; \\nsolvent effects; \\nacid–base equilibrium\",\"PeriodicalId\":20036,\"journal\":{\"name\":\"Patai's Chemistry of Functional Groups\",\"volume\":\"16 1\",\"pages\":\"1-61\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-09-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Patai's Chemistry of Functional Groups\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/9780470682531.PAT0937\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Patai's Chemistry of Functional Groups","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9780470682531.PAT0937","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Acid–Base and Solvation Properties of Metal Enolates Part 2: Transition-Metal Enolates and Medium Effects
This chapter presents the main aspects of acid–base reactions of transition-metal enolates and an overview of solvent effects on the chemical reactivity of metal enolates.
Keywords:
enolate ion;
transition-metal enolates;
metal Lewis acids;
dissociation constants;
solvent effects;
acid–base equilibrium
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