H. Kara
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Crystal Structure of Aqua[N,N′-bis(3-methoxysalicylidene)propane-1,2-diaminato]methanolmanganese(III) Perchlorate
The title compound, a hydrogen-bonded pseudo-dimer, Mn(C19H18N2O4)(CH4O)(H2O)]ClO4, (I), has been structurally characterized. Complex (I) affords an elongated octahedral coordination environment, with axial Mn-O(CH3OH) = 2.296(5) and Mn-O(water) = 2.208(3)A.