复合纸用细菌纳米纤维素和软木浆

Yu. A. Gismatulina, V. Budaeva, A. E. Sitnikova, N. V. Bychin, E. K. Gladysheva, N. Shavyrkina, G. F. Mironova, Yu. V. Sevastyanova
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引用次数: 2

摘要

摘要/ Abstract摘要:细菌纳米纤维素(BNC)的规模化生物合成可以获得BNC比例增加的复合纸样品。本研究旨在研究BNC样品和漂白软木硫酸盐纸浆(BSKP)复合纸,其组分的比例在很大范围内变化:10:90,30:70,50:50,60:40,70:30,90:10。通过对BNC:BSKP比例为20:80的复合材料试样的强度和变形性能的测定,选择了造纸方法。与参考样品相比,BNT在BSKP手板上的表面应用提供了强度值(抗撕裂性-提高37%,破裂指数-提高17%)和变形特性(拉伸刚度-提高66%,断裂功-提高8%,断裂长度-提高4%)的增加。所有样品均证实了复合材料的形成。扫描电子能谱分析表明,纸复合材料由交错的微BSKP和纳米BNC纤维组成。随着复合材料中BNC的比例增加,由于交联纳米元素的比例增加,结构致密化。红外光谱分析表明,所有样品的纤维素结构相似。结果发现,复合纸聚合度的增加与样品中BNC量的增加成正比。研究了复合纸样品对吉氏美度菌Sa-12发酵液中微生物的过滤能力。值得注意的是,当复合纸中BNC含量达到70%时,酵母保留率达到了100%。新材料的性能决定了其在过滤微生物方面的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Bacterial nanocellulose and softwood pulp for composite paper
Abstract: Scaling biosynthesis of bacterial nanocellulose (BNC) allowed samples of composite paper with an increased proportion of BNC to be obtained. This work aims to study BNC samples and bleached soft wood kraft pulp (BSKP) composite paper with a ratio of components varying across a wide range: 10:90, 30:70, 50:50, 60:40, 70:30, 90:10. The method of paper manufacturing was chosen based on the determinations of strength and deformation properties of composite samples with the BNC:BSKP ratio of 20:80. Surface application of BNT on BSKP handsheet provided for an increase in the strength values (tear resistance – by 37%, burst index – by 17%) and deformation characteristics (tension stiffness – by 66%, fracture work – by 8%, breaking length – by 4%) compared to a reference sample. The formation of composites is confirmed in all samples. Scanning electron spectroscopy revealed that paper composites comprise interlaced micro BSKP and nano BNC fibres. As the proportion of BNC in composites elevated, densification of the structure was observed due to an increased fraction of cross-linked nanosized elements. IR spectroscopy indicated the resemblance of cellulose structure in all samples. It was found that an increase in the degree of polymerisation of composite paper is directly proportional to an increase in the BNC amount in the samples. The filtering ability of composite paper samples against microorganisms in the culture liquid of the Medusomyces gisevii Sa-12 producer was studied. It should be noted that yeast retention is achieved with 70% BNC in the paper composite. The presented properties of the new material determine prospects for its use in filtering microorganisms.
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