{"title":"N-(甲基)脲与NaCN的反应:合成及机理研究","authors":"A. Fesenko, A. Shutalev","doi":"10.3390/ecsoc-25-11759","DOIUrl":null,"url":null,"abstract":": Reaction of NaCN with N -(tosylmethyl)ureas, prepared by condensation of urea with aldehydes and p -toluenesulfinic acid, has been studied. Generally, this reaction afforded the corresponding α -ureido nitriles. Some mechanistic aspects of cyanide-anion amidoalkylation with N -(to-sylmethyl)ureas were discussed based on DFT calculations.","PeriodicalId":11441,"journal":{"name":"ECSOC-25","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2021-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Reaction of N-(tosylmethyl)ureas with NaCN: Synthetic and Mechanistic Aspects\",\"authors\":\"A. Fesenko, A. Shutalev\",\"doi\":\"10.3390/ecsoc-25-11759\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": Reaction of NaCN with N -(tosylmethyl)ureas, prepared by condensation of urea with aldehydes and p -toluenesulfinic acid, has been studied. Generally, this reaction afforded the corresponding α -ureido nitriles. Some mechanistic aspects of cyanide-anion amidoalkylation with N -(to-sylmethyl)ureas were discussed based on DFT calculations.\",\"PeriodicalId\":11441,\"journal\":{\"name\":\"ECSOC-25\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-11-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ECSOC-25\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/ecsoc-25-11759\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ECSOC-25","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/ecsoc-25-11759","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Reaction of N-(tosylmethyl)ureas with NaCN: Synthetic and Mechanistic Aspects
: Reaction of NaCN with N -(tosylmethyl)ureas, prepared by condensation of urea with aldehydes and p -toluenesulfinic acid, has been studied. Generally, this reaction afforded the corresponding α -ureido nitriles. Some mechanistic aspects of cyanide-anion amidoalkylation with N -(to-sylmethyl)ureas were discussed based on DFT calculations.
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