有机金属化合物的微观可逆性和对称同位素交换反应

Journal of The Chemical Society B: Physical Organic Pub Date : 1971-01-01 DOI:10.1039/J29710000762

M. Abraham, D. Dodd, Michael D. Johnson, E. Lewis, R. O'Ferrall

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引用次数: 2

摘要

最近对有机汞-(II)化合物同位素交换反应机制解释的批评已经被证明是错误的，因为考虑到三维势能面，它显示了几种可能的反应路径。该方法为应用于对称有机金属交换反应的微观可逆性原理提供了清晰的理解。

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Microscopic reversibility and the symmetrical isotopic exchange reactions of organometallic compounds

Recent criticisms of well established mechanistic interpretations of isotopic exchange reactions of organomercury-(II) compounds have been shown to be erroneous by consideration of three-dimensional potential-energy surfaces, which show the several possible reaction paths. The method provides a clear understanding of the principle of microscopic reversibility as applied to symmetrical organometallic exchange reactions.

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Journal of The Chemical Society B: Physical Organic

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