高荧光杂环染料的激发态电子和能量转移:激光闪光光解2,5-二甲基-3,6-二苯基吡咯[3,4-c]吡咯-1,4-二酮的研究

V. Srivatsavoy, M. Eschle, J. Moser, M. Grätzel
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引用次数: 5

摘要

报道了标题化合物的三重态和单线态性质:硝基自由基和氧显著提高了三重态产率;在乙腈中,电子从单线态激发态转移到甲基紫酮产生了相应的自由基,并在二级动力学中重组。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Excited state electron and energy transfer of a highly fluorescent heterocyclic dye: a laser flash photolysis study of 2,5-dimethyl-3,6-diphenylpyrrolo[3,4-c]pyrrole-1,4-dione
The triplet and singlet state properties of the title compound are reported: nitroxyl free radicals and oxygen enhance the triplet yield significantly; electron transfer from the singlet excited state to methyl viologen in acetonitrile produced the corresponding free radicals which recombine with second-order kinetics.
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