甲基苯过渡金属三羰基晶体结构与羰基键伸缩振动的关系

Discussions of The Faraday Society Pub Date : 1969-01-01 DOI:10.1039/DF9694700048

H. Buttery, G. Keeling, S. Kettle, I. Paul, P. J. Stamper

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引用次数: 9

摘要

比较了金属羰基固体红外光谱和拉曼光谱解释的位元法和因子群法。对七个芳烃铬三羰基的因子群分析表明，振动重复单元的有效对称性可能高于晶体学点群的有效对称性。

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Correlation between crystal structure and carbonyl-bond stretching vibrations of methyl benzene transition metal tricarbonyls

The site and factor group approaches to the interpretation of solid state infra-red and Raman spectra of metal carbonyls are compared. A factor group analysis of seven arene chromium tri-carbonyls indicates that the effective symmetry of the vibrational repeating unit may be higher than that of the crystallographic point group.

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Discussions of The Faraday Society

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