I. Jaya, Intan Syahbanu, Nelly Wahyuni
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引用次数: 0

摘要

锂(Li)作为电池阴极的主要材料,其来源有限已成为新能源和可再生能源(EBT)发展中的一个问题。根据它们在地球上的还原潜力和可用性,可能被怀疑的元素包括钾(K)、钠(Na)、镁(Mg)和钙(Ca)。所有这些都不能从天然原料中获得,其中之一就是金发女郎。Blondo是椰子油加工的副产品,没有得到最佳的利用。本研究采用不同时间(5、7、9小时)和温度(450、550、650℃)的煅烧工艺,从blondo中获得最佳的氧化物化合物。用组成比为20:1的blondo和聚乙烯醇(PVA)的混合物制作阴极,并附着在不锈钢板上。利用x射线荧光(XRF)对氧化化合物的百分比进行了测试,结果表明,煅烧过程使氧化化合物的百分比水平增加了K2O, P2O5, MgO和Cl。然而,当煅烧时间和温度增加时,它对先前产生的氧化物化合物的水平没有太大的影响。x射线衍射(XRD)结果表明,煅烧温度越高,氧化物的晶体尺寸越小。在450、550和650℃的温度下,产率为50.0;47.5和36.4纳米。这也得到了XRF测试结果的支持,其中K2O是焙烧金发中氧化物化合物的最主要成分。作为正极材料进行了三次循环测试,平均充电容量为14.67 mAh,平均放电容量为5.34 mAh,平均效率为55.68%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
POTENSI SENYAWA OKSIDA DARI BLONDO SEBAGAI KATODA BATERAI (POTENCY OF OXIDE COMPOUNDS FROM BLONDO AS BATTERY CATHODE)
The limited source of Lithium (Li) as the main material for battery cathodes has become a problem in the development of the new and renewable energy (EBT) sector. Based on their reduction potential and availability on earth, elements that might be suspected include Potassium (K), Sodium (Na), Magnesium (Mg) and Calcium (Ca). All cannot be obtained from natural ingredients, one of which is blondo. Blondo is a by-product of coconut oil processing that has not been used optimally. This study used the calcination process by varying the time (5, 7, 9 hours) and temperature (450, 550, 650°C) to obtain optimal oxide compounds from blondo. Making the cathode using a mixture of blondo and Polvinyl Alcohol (PVA) with a composition ratio of 20:1 attached to a stainless steel plate. Testing the percentage of oxide compounds was carried out using X-Ray Fluorescence (XRF) which showed that the calcination process caused the percentage levels of oxide compounds to increase K2O, P2O5, MgO and Cl. However, when the calcination time and temperature were increased, it did not give a much different effect on the levels of oxide compounds produced previously. The effect of calcination temperature is known from the results of X-Ray Diffraction (XRD) which shows that the higher the calcination temperature, the smaller the crystal size of the oxide compound. At temperatures of 450, 550 and 650°C the yields are 50.0; 47.5 and 36.4 nm. This is also supported by the results of XRF testing where K2O is the most dominant component of the oxide compound in calcined blondo. The test as a cathode material was carried out for three cycles resulting in an average charge capacity of 14.67 mAh, and an average discharge capacity of 5.34 mAh so that the average efficiency was 55.68%.
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