麻风树油连续生产生物柴油的高效微混合

Waleed S. Mohammed, A. El‐Shazly, M. Elkady, M. Ohshima
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引用次数: 1

摘要

由于世界范围内的能源短缺,生物柴油作为一种替代燃料的利用正变得越来越出名。利用麻风树作为非食油原料的热情正在迅速发展。考虑到该技术具有较高的传质系数,通过微反应器连续化可以提高碱催化甲醇分解反应的性能。采用溶胶-凝胶法制备了纳米钨钒酸锆,并将其作为生物柴油生产的补充步骤。所制备材料的平均直径为0.066 &µm。首先,在连续微反应器中研究了NaOH催化麻疯树油的甲醇分解,并研究了不同搅拌器在不同条件下的高效混合及其对生物柴油产量的影响。其次,考察了纳米催化剂作为二级催化剂的添加效果。在甲醇与麻疯树油摩尔比为11的条件下,在60℃、1% NaOH条件下,在94 s内得到麻疯树油甲酯的最大收率为98.1%。仅用0.3%的NaOH,纳米催化剂的转化率也达到了同样的最大值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Efficient Micromixing for Continuous Biodiesel Production from Jatropha Oil
The utilization of biodiesel as an alternative fuel is turning out to be progressively famous these days because of worldwide energy deficiency. The enthusiasm for utilizing Jatropha as a non-edible oil feedstock is quickly developing. The performance of the base catalyzed methanolysis reaction could be improved by a continuous process through a microreactor in view of the high mass transfer coefficient of this technique. Nanozirconium tungstovanadate, which was synthetized using sol-gel preparation method, was utilized in a complementary step for biodiesel production process. The prepared material has an average diameter of 0.066 &µm. First, the NaOH catalyzed methanolysis of Jatropha oil was investigated in a continuous microreactor, and the efficient mixing over different mixers and its impact on the biodiesel yield were studied under varied conditions. Second, the effect of adding the nanocatalyst as a second stage was investigated. The maximum percentage of produced methyl esters from Jatropha oil was 98.1% using a methanol/Jatropha oil molar ratio of 11 within 94 s using 1% NaOH at 60 &°C. The same maximum conversion ratio was recorded with the nanocatalyst via only 0.3% NaOH.
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