支链高分子材料在燃料电池质子交换膜中的应用

IF 11.1 2区化学 Q1 POLYMER SCIENCE

Polymer Reviews Pub Date : 2021-08-15 DOI:10.1080/15583724.2021.1964524

S. Neelakandan, Li Wang, Boping Zhang, Jiangpeng Ni, Meishao Hu, Chunmei Gao, Wai-Yeung Wong, Lei Wang

{"title":"支链高分子材料在燃料电池质子交换膜中的应用","authors":"S. Neelakandan, Li Wang, Boping Zhang, Jiangpeng Ni, Meishao Hu, Chunmei Gao, Wai-Yeung Wong, Lei Wang","doi":"10.1080/15583724.2021.1964524","DOIUrl":null,"url":null,"abstract":"Abstract Recent progress on branched polymer membranes as electrolyte materials for proton exchange membrane fuel cell (PEMFC) applications has attracted interest due to the limitations of commercially available Nafion® membranes. Branched polymer membranes have shown improved chemical stability, proton conductivity, and good solubility. The branching degree and the structure of the branching agent have an essential correlation with the characteristics of the polymer membranes. This review presents the most recent and promising design strategies and characteristics of branched polymers as proton exchange membranes for both low- and high-temperature proton exchange membrane fuel cells. Recent advances in branched polymers are summarized, including branched sulfonated poly(aryl ether)s, branched sulfonated polyimides, branched polybenzimidazoles, etc. The remaining challenges and prospects in proton exchange membranes are also discussed.","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"272 1","pages":"261 - 295"},"PeriodicalIF":11.1000,"publicationDate":"2021-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"25","resultStr":"{\"title\":\"Branched Polymer Materials as Proton Exchange Membranes for Fuel Cell Applications\",\"authors\":\"S. Neelakandan, Li Wang, Boping Zhang, Jiangpeng Ni, Meishao Hu, Chunmei Gao, Wai-Yeung Wong, Lei Wang\",\"doi\":\"10.1080/15583724.2021.1964524\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Recent progress on branched polymer membranes as electrolyte materials for proton exchange membrane fuel cell (PEMFC) applications has attracted interest due to the limitations of commercially available Nafion® membranes. Branched polymer membranes have shown improved chemical stability, proton conductivity, and good solubility. The branching degree and the structure of the branching agent have an essential correlation with the characteristics of the polymer membranes. This review presents the most recent and promising design strategies and characteristics of branched polymers as proton exchange membranes for both low- and high-temperature proton exchange membrane fuel cells. Recent advances in branched polymers are summarized, including branched sulfonated poly(aryl ether)s, branched sulfonated polyimides, branched polybenzimidazoles, etc. The remaining challenges and prospects in proton exchange membranes are also discussed.\",\"PeriodicalId\":20326,\"journal\":{\"name\":\"Polymer Reviews\",\"volume\":\"272 1\",\"pages\":\"261 - 295\"},\"PeriodicalIF\":11.1000,\"publicationDate\":\"2021-08-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"25\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/15583724.2021.1964524\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Reviews","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/15583724.2021.1964524","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}

引用次数: 25

摘要

支链聚合物膜作为质子交换膜燃料电池(PEMFC)电解质材料的最新进展引起了人们的兴趣，这是由于市面上可用的Nafion®膜的局限性。支化聚合物膜表现出更好的化学稳定性、质子导电性和良好的溶解性。支化剂的支化程度和支化剂的结构与聚合物膜的特性有本质的关系。本文综述了支链聚合物作为低温和高温质子交换膜燃料电池中质子交换膜的最新设计策略和特点。综述了支化聚合物的研究进展，包括支化磺化聚芳基醚、支化磺化聚酰亚胺、支化聚苯并咪唑等。最后讨论了质子交换膜存在的挑战和发展前景。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Branched Polymer Materials as Proton Exchange Membranes for Fuel Cell Applications

Abstract Recent progress on branched polymer membranes as electrolyte materials for proton exchange membrane fuel cell (PEMFC) applications has attracted interest due to the limitations of commercially available Nafion® membranes. Branched polymer membranes have shown improved chemical stability, proton conductivity, and good solubility. The branching degree and the structure of the branching agent have an essential correlation with the characteristics of the polymer membranes. This review presents the most recent and promising design strategies and characteristics of branched polymers as proton exchange membranes for both low- and high-temperature proton exchange membrane fuel cells. Recent advances in branched polymers are summarized, including branched sulfonated poly(aryl ether)s, branched sulfonated polyimides, branched polybenzimidazoles, etc. The remaining challenges and prospects in proton exchange membranes are also discussed.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Polymer Reviews 工程技术-高分子科学

CiteScore

24.80

自引率

0.80%

发文量

审稿时长

6 months

期刊介绍： Polymer Reviews is a reputable publication that focuses on timely issues within the field of macromolecular science and engineering. The journal features high-quality reviews that have been specifically curated by experts in the field. Topics of particular importance include biomedical applications, organic electronics and photonics, nanostructures, micro- and nano-fabrication, biological molecules (such as DNA, proteins, and carbohydrates), polymers for renewable energy and environmental applications, and interdisciplinary intersections involving polymers. The articles in Polymer Reviews fall into two main categories. Some articles offer comprehensive and expansive overviews of a particular subject, while others zero in on the author's own research and situate it within the broader scientific landscape. In both types of articles, the aim is to provide readers with valuable insights and advancements in the field of macromolecular science and engineering.