铬酸铜(II)的振动和电子光谱

Spectrochimica acta. Part A: Molecular spectroscopy Pub Date : 1994-12-01 DOI:10.1016/0584-8539(94)E0001-Q

Enrique J. Baran

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引用次数: 12

摘要

记录了CuCrO4的红外光谱、拉曼光谱和电子(反射)光谱。在因子群分析的帮助下，确定了CrO2−4离子的内部振动。CuIIO6基团的“d-d”跃迁和O→Cu的一个电荷转移带也可以被分配。并与其它结构相关的化合物作了比较。

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Vibrational and electronic spectra of copper(II) chromate

The infrared, Raman and electronic (reflectance) spectra of CuCrO₄ were recorded. The internal vibrations of the CrO²⁻₄ ions were assigned with the aid of a factor group analysis. The ‘d-d’ transitions of the Cu^IIO₆ moieties and one of the O → Cu charge transfer bands could also be assigned. Some comparisons with other structurally related compounds are made.

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Spectrochimica acta. Part A: Molecular spectroscopy

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