高可靠性工程铜SMT粘接材料

A. Zinn, R. Stoltenberg, Reynaldo Joven, Nhi K. Ngo, Alexander Capanzana
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摘要

我们开始确认一种新型纳米铜基高导电性粘结剂的高可靠性,该粘结剂允许制定一整套可调工程铜(TEC)浆料和油墨,适用于广泛的SMT模粘接和封装应用。在本文中,我们提供了3×3 mm碳化硅(SiC)模具与图像化直接键合铜(DBC)氮化铝(AlN)衬底结合的综合热循环和热冲击数据。我们发现,在3个不同的测试系列中,超过100个设备的100%存活率证实了TEC提供的高可靠性。部分部件在热处理后甚至可以承受100 kg (>110 MPa)的剪切载荷而不失效。与普通锡基焊料和烧结银相比,无压熔融铜界面具有优越的电导率(高达70% IACS)和热导电性(高达330 W/m·K)。因此,TEC首次提供了一种可行的全铜SMT材料,完全将工艺温度与工作温度脱钩,使全铜封装系统能够消除脆性IMC形成。高温稳定性已经测试到500°C以上。由于这些特性,它大大优于烧结银,并且在熔合过程中无需压力即可加工,只需几分钟的加工时间。TEC已经开发了10多年,最近已经成熟到可以集成到商业产品中。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
High Reliability Engineered Copper SMT Bonding Material
We set out to affirm the high reliability of a novel nanocopper-based highly conductive bond agent that allows the formulation of an entire suite of Tunable Engineered Copper (TEC) pastes and inks suited for a wide range of SMT die-bonding and packaging applications. In this paper, we present comprehensive thermal cycling and thermal shock data on 3×3 mm silicon carbide (SiC) dies bonded to patterned direct-bond copper (DBC) aluminum nitride (AlN) substrates. We found a 100% survival rate for over 100 devices tested across 3 different test series substantiating the high reliability provided by TEC. Some parts even survived repeated 100 kg shear loads (>110 MPa) after thermal treatment without failing. The pressure-less, fused-copper interfaces exhibit superior electrical (as high as 70% IACS) and thermal (as high as 330 W/m·K) conductivity compared to common tin-based solders and sintered silver. Therefore, TEC offers for the first time a viable all-copper SMT material completely decoupling process-temperature from operating temperature that enables all-copper packaging systems that eliminates brittle IMC formation. High-temperature stability has already been tested to over 500°C. With these properties, it is vastly superior to sintered silver and processable without the need for pressure during fusion with just a few minutes processing time. TEC has been under development for over 10 years and recently matured to the point that it can be integrated into commercial products.
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