Joon-soo Kim, Seungwon Lee, Y. Hwang, Yongho Kim, S. Yoo, B. Bae
{"title":"用硫烯在空气或N2中反应光固化溶胶-凝胶杂化膜作为有机薄膜晶体管的介电层","authors":"Joon-soo Kim, Seungwon Lee, Y. Hwang, Yongho Kim, S. Yoo, B. Bae","doi":"10.1149/2.021205ESL","DOIUrl":null,"url":null,"abstract":"Sol-gel derived oligosiloxane resins are cured under air or N2 by a photo-initiated thiol-ene reaction. The cured film was fabricated as a dielectric layer for use in an organic thin film transistor, and offers a higher dielectric constant (4.13) than silicon dioxide (3.9). We investigated the effects of the curing conditions of a thiol-ene reaction on the TFT performance depending on air or N2. In the N2 conditions, hydroperoxide group (−OOH) free films were generated and they showed low leakage current density and hysteresis free behavior with higher mobility than those fabricated in air. © 2012 The Electrochemical Society. [DOI: 10.1149/2.021205esl] All rights reserved.","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"73 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Photo-Curable Sol-Gel Hybrid Film as a Dielectric Layer by a Thiol-ene Reaction in Air or N2 for Organic Thin Film Transistors\",\"authors\":\"Joon-soo Kim, Seungwon Lee, Y. Hwang, Yongho Kim, S. Yoo, B. Bae\",\"doi\":\"10.1149/2.021205ESL\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Sol-gel derived oligosiloxane resins are cured under air or N2 by a photo-initiated thiol-ene reaction. The cured film was fabricated as a dielectric layer for use in an organic thin film transistor, and offers a higher dielectric constant (4.13) than silicon dioxide (3.9). We investigated the effects of the curing conditions of a thiol-ene reaction on the TFT performance depending on air or N2. In the N2 conditions, hydroperoxide group (−OOH) free films were generated and they showed low leakage current density and hysteresis free behavior with higher mobility than those fabricated in air. © 2012 The Electrochemical Society. [DOI: 10.1149/2.021205esl] All rights reserved.\",\"PeriodicalId\":11627,\"journal\":{\"name\":\"Electrochemical and Solid State Letters\",\"volume\":\"73 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2012-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Electrochemical and Solid State Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1149/2.021205ESL\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrochemical and Solid State Letters","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1149/2.021205ESL","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6