中富勒烯从C32到C60生长的几何模型

IF 0.2 Q4 PHYSICS, MULTIDISCIPLINARY
Alexander I. Melker, Maria A. Krupina
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引用次数: 10

摘要

轴测投影和富勒烯的相应图形在32到60的范围内构造。根据碳二聚体嵌入初始富勒烯六边形的机理,研究了富勒烯的生长。这导致了与产生张力平行的共价键的拉伸和断裂。在这种情况下,得到的不是一个六边形邻接两个五边形,而是两个相邻的五边形邻接两个六边形。结果,产生了新的原子构型,两个碳原子的质量增加。我们考虑了富勒烯C32的直系后代;即C2n,其中n = 17-30。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Geometric modeling of midi-fullerene growth from C32 to C60

Axonometric projections together with the corresponding graphs for fullerenes are constructed in the range from 32 to 60. The growth of fullerenes is studied on the basis of a mechanism according to which a carbon dimer embeds in a hexagon of an initial fullerene. This leads to stretching and breaking the covalent bonds which are parallel to arising tensile forces. In this case, instead of a hexagon adjoining two pentagons, two adjacent pentagons adjoining two hexagons are obtained. As a result, there arises a new atomic configuration and there is mass increase of two carbon atoms. We considered the direct descendants of fullerene C32; namely, C2n, where n = 17–30.

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