含有呋喃基团的聚酰胺。1. 2,2 ' -双(5-氯甲酰基-2-呋喃基)丙烷与1,6-二氨基己烷的界面缩聚

S. Gharbi, A. Gandini
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引用次数: 23

摘要

系统地研究了2,2′-双(5-氯甲酰基- 2-呋喃基)丙烷与六亚乙二胺界面缩聚合成呋喃脂肪族聚酰胺过程中各参数的影响。讨论了有机溶剂、温度、相转移催化剂类型、单体和氢氧化钠浓度等因素对反应的影响。所得聚酰胺的固有粘度高于文献报道的由呋喃-2,5-二羧酸合成的呋喃脂肪族聚酰胺的固有粘度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Polyamides incorporating furan moieties. 1. Interfacial polycondensation of 2,2′-bis(5-chloroformyl-2-furyl)propane with 1,6-diaminohexane

A systematic study, devoted to analyzing the effect of various parameters in the synthesis of furanic aliphatic polyamide by interfacial polycondensation of 2,2′-bis(5-chloroformyl 2-furyl)propane with hexamethylene diamine, is described. The effects of the organic solvent, temperature and phase transfer catalyst type, as well as monomer and sodium hydroxyde concentrations are discussed. The inherent viscosity of the polyamide obtained is higher than those reported in the literature for furanic aliphatic polyamides synthesized from furan-2,5-dicarboxylic acid.

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