{"title":"含有呋喃基团的聚酰胺。1. 2,2 ' -双(5-氯甲酰基-2-呋喃基)丙烷与1,6-二氨基己烷的界面缩聚","authors":"S. Gharbi, A. Gandini","doi":"10.1002/(SICI)1521-4044(19990801)50:8<293::AID-APOL293>3.0.CO;2-I","DOIUrl":null,"url":null,"abstract":"<p>A systematic study, devoted to analyzing the effect of various parameters in the synthesis of furanic aliphatic polyamide by interfacial polycondensation of 2,2′-bis(5-chloroformyl 2-furyl)propane with hexamethylene diamine, is described. The effects of the organic solvent, temperature and phase transfer catalyst type, as well as monomer and sodium hydroxyde concentrations are discussed. The inherent viscosity of the polyamide obtained is higher than those reported in the literature for furanic aliphatic polyamides synthesized from furan-2,5-dicarboxylic acid.</p>","PeriodicalId":7162,"journal":{"name":"Acta Polymerica","volume":"50 8","pages":"293-297"},"PeriodicalIF":0.0000,"publicationDate":"1999-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"23","resultStr":"{\"title\":\"Polyamides incorporating furan moieties. 1. Interfacial polycondensation of 2,2′-bis(5-chloroformyl-2-furyl)propane with 1,6-diaminohexane\",\"authors\":\"S. Gharbi, A. Gandini\",\"doi\":\"10.1002/(SICI)1521-4044(19990801)50:8<293::AID-APOL293>3.0.CO;2-I\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A systematic study, devoted to analyzing the effect of various parameters in the synthesis of furanic aliphatic polyamide by interfacial polycondensation of 2,2′-bis(5-chloroformyl 2-furyl)propane with hexamethylene diamine, is described. The effects of the organic solvent, temperature and phase transfer catalyst type, as well as monomer and sodium hydroxyde concentrations are discussed. The inherent viscosity of the polyamide obtained is higher than those reported in the literature for furanic aliphatic polyamides synthesized from furan-2,5-dicarboxylic acid.</p>\",\"PeriodicalId\":7162,\"journal\":{\"name\":\"Acta Polymerica\",\"volume\":\"50 8\",\"pages\":\"293-297\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1999-08-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"23\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Polymerica\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/%28SICI%291521-4044%2819990801%2950%3A8%3C293%3A%3AAID-APOL293%3E3.0.CO%3B2-I\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Polymerica","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/%28SICI%291521-4044%2819990801%2950%3A8%3C293%3A%3AAID-APOL293%3E3.0.CO%3B2-I","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Polyamides incorporating furan moieties. 1. Interfacial polycondensation of 2,2′-bis(5-chloroformyl-2-furyl)propane with 1,6-diaminohexane
A systematic study, devoted to analyzing the effect of various parameters in the synthesis of furanic aliphatic polyamide by interfacial polycondensation of 2,2′-bis(5-chloroformyl 2-furyl)propane with hexamethylene diamine, is described. The effects of the organic solvent, temperature and phase transfer catalyst type, as well as monomer and sodium hydroxyde concentrations are discussed. The inherent viscosity of the polyamide obtained is higher than those reported in the literature for furanic aliphatic polyamides synthesized from furan-2,5-dicarboxylic acid.