{"title":"微波辅助合成纳米钯及其在铃木偶联反应中的催化应用","authors":"Jian Zhang, X. Bai","doi":"10.2174/1874088X01711010001","DOIUrl":null,"url":null,"abstract":"A facile and efficient method was developed for the synthesis of highly active palladium nanoparticles (PdNPs) by microwave-assisted chemical reduction. The PdNPs with different morphology were prepared with or without KBr (capping agent) using ethylene glycol (EG) and citric acid (CA) as reducing agent in the presence of polyvinylpyrrolidone (PVP), respectively. The as-prepared PdNPs were characterized by (UV-Visible Spectrophotometer) UV-Vis, transmission electron microscopy (TEM) and Xray diffraction (XRD) analysis. The results showed that the PdNPs reduced by EG without KBr (PdNPs-EG) has smaller particle size than other PdNPs. The remarkable catalytic activity of the PdNPs catalysts are obtained using a low amount of PdNPs (0.1 mmol‰) using K2CO3 as base and EtOH/H2O as solvent toward Suzuki coupling reactions of aryl bromides and phenylboronic acid for 15 min.","PeriodicalId":22791,"journal":{"name":"The Open Materials Science Journal","volume":"257 1","pages":"1-8"},"PeriodicalIF":0.0000,"publicationDate":"2017-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Microwave-Assisted Synthesis of Pd Nanoparticles and Catalysis Application for Suzuki Coupling Reactions\",\"authors\":\"Jian Zhang, X. Bai\",\"doi\":\"10.2174/1874088X01711010001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A facile and efficient method was developed for the synthesis of highly active palladium nanoparticles (PdNPs) by microwave-assisted chemical reduction. The PdNPs with different morphology were prepared with or without KBr (capping agent) using ethylene glycol (EG) and citric acid (CA) as reducing agent in the presence of polyvinylpyrrolidone (PVP), respectively. The as-prepared PdNPs were characterized by (UV-Visible Spectrophotometer) UV-Vis, transmission electron microscopy (TEM) and Xray diffraction (XRD) analysis. The results showed that the PdNPs reduced by EG without KBr (PdNPs-EG) has smaller particle size than other PdNPs. The remarkable catalytic activity of the PdNPs catalysts are obtained using a low amount of PdNPs (0.1 mmol‰) using K2CO3 as base and EtOH/H2O as solvent toward Suzuki coupling reactions of aryl bromides and phenylboronic acid for 15 min.\",\"PeriodicalId\":22791,\"journal\":{\"name\":\"The Open Materials Science Journal\",\"volume\":\"257 1\",\"pages\":\"1-8\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-02-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Open Materials Science Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/1874088X01711010001\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Materials Science Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1874088X01711010001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Microwave-Assisted Synthesis of Pd Nanoparticles and Catalysis Application for Suzuki Coupling Reactions
A facile and efficient method was developed for the synthesis of highly active palladium nanoparticles (PdNPs) by microwave-assisted chemical reduction. The PdNPs with different morphology were prepared with or without KBr (capping agent) using ethylene glycol (EG) and citric acid (CA) as reducing agent in the presence of polyvinylpyrrolidone (PVP), respectively. The as-prepared PdNPs were characterized by (UV-Visible Spectrophotometer) UV-Vis, transmission electron microscopy (TEM) and Xray diffraction (XRD) analysis. The results showed that the PdNPs reduced by EG without KBr (PdNPs-EG) has smaller particle size than other PdNPs. The remarkable catalytic activity of the PdNPs catalysts are obtained using a low amount of PdNPs (0.1 mmol‰) using K2CO3 as base and EtOH/H2O as solvent toward Suzuki coupling reactions of aryl bromides and phenylboronic acid for 15 min.
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