{"title":"钯固定菲罗啉-2,9-二甲醛修饰的磁性 CuBDC MOF 作为可重复使用的异构催化剂用于铃木-宫浦交叉偶联反应","authors":"","doi":"10.1080/10406638.2023.2244632","DOIUrl":null,"url":null,"abstract":"<div><p>A porous magnetic multifunctional copper-based metal-organic framework (MOF) was developed through combined covalent and dative post-synthetic modification (PSM) of the CuBDC. In this regard, a novel magnetic metal-organic framework (MMOF) consisting of supported 1,10-phenanthroline-2,9-dicarbaldehyde (Fe<sub>3</sub>O<sub>4</sub>@Cu(BDC)-NH<sub>2</sub>-PHD) has been fabricated by post-synthetic modifications of Fe<sub>3</sub>O<sub>4</sub>@Cu(BDC)-NH<sub>2</sub>. Subsequently, the prepared nanocomposites were modified using palladium chloride ions (Fe<sub>3</sub>O<sub>4</sub>@Cu(BDC)-NH<sub>2</sub>-PdPHD) to impart catalytic sites. As a result, the fabricated magnetic porous catalyst exhibited great catalytic activity in Suzuki-Miyaura cross-coupling reactions. Some of the essential advantages of the synthesized catalyst are; high catalytic activity, short reaction times, mild conditions, high thermal stability, and reusability. Moreover, his porous magnetic nanomaterial can be used as a new support to immobilize other metals in different catalytic reactions.</p></div>","PeriodicalId":20303,"journal":{"name":"Polycyclic Aromatic Compounds","volume":"44 6","pages":"Pages 4065-4080"},"PeriodicalIF":2.4000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pd Immobilization Phenanthroline-2,9-Dicarbaldehyde Modified Magnetic CuBDC MOF as a Reusable Heterogeneous Catalyst for Suzuki-Miyaura Cross-Coupling Reactions\",\"authors\":\"\",\"doi\":\"10.1080/10406638.2023.2244632\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A porous magnetic multifunctional copper-based metal-organic framework (MOF) was developed through combined covalent and dative post-synthetic modification (PSM) of the CuBDC. In this regard, a novel magnetic metal-organic framework (MMOF) consisting of supported 1,10-phenanthroline-2,9-dicarbaldehyde (Fe<sub>3</sub>O<sub>4</sub>@Cu(BDC)-NH<sub>2</sub>-PHD) has been fabricated by post-synthetic modifications of Fe<sub>3</sub>O<sub>4</sub>@Cu(BDC)-NH<sub>2</sub>. Subsequently, the prepared nanocomposites were modified using palladium chloride ions (Fe<sub>3</sub>O<sub>4</sub>@Cu(BDC)-NH<sub>2</sub>-PdPHD) to impart catalytic sites. As a result, the fabricated magnetic porous catalyst exhibited great catalytic activity in Suzuki-Miyaura cross-coupling reactions. Some of the essential advantages of the synthesized catalyst are; high catalytic activity, short reaction times, mild conditions, high thermal stability, and reusability. Moreover, his porous magnetic nanomaterial can be used as a new support to immobilize other metals in different catalytic reactions.</p></div>\",\"PeriodicalId\":20303,\"journal\":{\"name\":\"Polycyclic Aromatic Compounds\",\"volume\":\"44 6\",\"pages\":\"Pages 4065-4080\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2024-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polycyclic Aromatic Compounds\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1040663823019796\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polycyclic Aromatic Compounds","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1040663823019796","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Pd Immobilization Phenanthroline-2,9-Dicarbaldehyde Modified Magnetic CuBDC MOF as a Reusable Heterogeneous Catalyst for Suzuki-Miyaura Cross-Coupling Reactions
A porous magnetic multifunctional copper-based metal-organic framework (MOF) was developed through combined covalent and dative post-synthetic modification (PSM) of the CuBDC. In this regard, a novel magnetic metal-organic framework (MMOF) consisting of supported 1,10-phenanthroline-2,9-dicarbaldehyde (Fe3O4@Cu(BDC)-NH2-PHD) has been fabricated by post-synthetic modifications of Fe3O4@Cu(BDC)-NH2. Subsequently, the prepared nanocomposites were modified using palladium chloride ions (Fe3O4@Cu(BDC)-NH2-PdPHD) to impart catalytic sites. As a result, the fabricated magnetic porous catalyst exhibited great catalytic activity in Suzuki-Miyaura cross-coupling reactions. Some of the essential advantages of the synthesized catalyst are; high catalytic activity, short reaction times, mild conditions, high thermal stability, and reusability. Moreover, his porous magnetic nanomaterial can be used as a new support to immobilize other metals in different catalytic reactions.
期刊介绍：
The purpose of Polycyclic Aromatic Compounds is to provide an international and interdisciplinary forum for all aspects of research related to polycyclic aromatic compounds (PAC). Topics range from fundamental research in chemistry (including synthetic and theoretical chemistry) and physics (including astrophysics), as well as thermodynamics, spectroscopy, analytical methods, and biology to applied studies in environmental science, biochemistry, toxicology, and industry. Polycyclic Aromatic Compounds has an outstanding Editorial Board and offers a rapid and efficient peer review process, as well as a flexible open access policy.
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