{"title":"铁(III)、镍(II)和钴(II)可聚合β-酮酯配合物催化烯烃有氧环氧化反应","authors":"P. Mastrorilli, C.F. Nobile","doi":"10.1016/0304-5102(94)87026-8","DOIUrl":null,"url":null,"abstract":"<div><p>Efficient epoxidation of olefinic compounds is achieved by using soluble polymerizable β-ketoesterate complexes. Iron(III), cobalt(II) and nickel(II) catalytic centres are utilized in 1,2-dichloroethane at ambient conditions. Oxygen or air and a branched aldehyde are employed as the oxidant and reductant respectively (Mukaiyama's conditions).</p></div>","PeriodicalId":16567,"journal":{"name":"分子催化","volume":"94 1","pages":"Pages 19-26"},"PeriodicalIF":0.0000,"publicationDate":"1994-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0304-5102(94)87026-8","citationCount":"22","resultStr":"{\"title\":\"Aerobic epoxidation of olefins catalyzed by polymerizable β-ketoesterate complexes of iron(III), nickel(II) and cobalt(II)\",\"authors\":\"P. Mastrorilli, C.F. Nobile\",\"doi\":\"10.1016/0304-5102(94)87026-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Efficient epoxidation of olefinic compounds is achieved by using soluble polymerizable β-ketoesterate complexes. Iron(III), cobalt(II) and nickel(II) catalytic centres are utilized in 1,2-dichloroethane at ambient conditions. Oxygen or air and a branched aldehyde are employed as the oxidant and reductant respectively (Mukaiyama's conditions).</p></div>\",\"PeriodicalId\":16567,\"journal\":{\"name\":\"分子催化\",\"volume\":\"94 1\",\"pages\":\"Pages 19-26\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0304-5102(94)87026-8\",\"citationCount\":\"22\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"分子催化\",\"FirstCategoryId\":\"1089\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0304510294870268\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"Chemical Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"分子催化","FirstCategoryId":"1089","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0304510294870268","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Chemical Engineering","Score":null,"Total":0}
Aerobic epoxidation of olefins catalyzed by polymerizable β-ketoesterate complexes of iron(III), nickel(II) and cobalt(II)
Efficient epoxidation of olefinic compounds is achieved by using soluble polymerizable β-ketoesterate complexes. Iron(III), cobalt(II) and nickel(II) catalytic centres are utilized in 1,2-dichloroethane at ambient conditions. Oxygen or air and a branched aldehyde are employed as the oxidant and reductant respectively (Mukaiyama's conditions).
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
