贵金属冶炼废水处理工艺优化研究

Liudmila V. Biketova, Iurii N. Lisakov, Sergei D. Ershov
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引用次数: 0

摘要

黄金生产中最普遍的方法是对精矿进行氰化浸出。俄罗斯联邦的大多数金矿位于极北和远东地区,其气候带的特点是正水平衡。在这方面,有必要解决废水处理问题。除氰化物的工艺是众所周知的,并在工业规模上得到了验证。精矿中有色金属硫化物和铁的存在导致硫氰酸盐生产引起的氰化物消耗增加。因此,金矿企业必须从氰化物和硫氰酸盐两个方面解决排放水的中和问题。这一问题目前在俄罗斯的业务中尤为突出,因为对处理过的废水中氰化物和硫氰酸盐含量的要求实际上是相称的。本文综述了国内外在含氰废水处理领域的研究成果,并对含硫氰酸盐废水的处理进行了综述。我们的研究表明,臭氧氧化废水具有很高的效率。结果表明,臭氧氧化过程运行速度快,并伴有氰化物再生。这节省了50%以上的臭氧生产成本,后者是该技术应用的主要经济限制因素。臭氧化技术确保了试剂和处理过的废水中间体不会产生二次污染。所开发的方法符合法规对废水中氰化物和硫氰酸盐含量的要求。由于缺乏试剂,该过程的成本较低,因此,购买和运送到金矿开采作业的成本较低,并且氰化物再生的潜力使该方法非常有吸引力。正常0 false false false RU X-NONE X-NONE /* Style Definitions */表。MsoNormalTable {mso-style-name:“Обычнаятаблица”;mso-tstyle-rowband-size: 0;mso-tstyle-colband-size: 0;mso-style-noshow:是的;mso-style-priority: 99;mso-style-parent:“”;Mso-padding-alt:0cm 5.4pt;mso-para-margin-top: 0厘米;mso-para-margin-right: 0厘米;mso-para-margin-bottom: 8.0分;mso-para-margin-left: 0厘米;行高:107%;mso-pagination: widow-orphan;字体大小:11.0分;字体类型:“Calibri”、“无衬线”;mso-ascii-font-family: Calibri;mso-ascii-theme-font: minor-latin;mso-hansi-font-family: Calibri;mso-hansi-theme-font: minor-latin;mso-fareast-language: en - us;}
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Development of the Optimal Wastewater Treatment Technologies Refining of Precious Metals
The most widespread method in gold production is cyanide leaching of ore concentrates. Most of gold ore deposits in the Russian Federation are located in the Far North and Far East with their climate zone characterized by a positive water balance. In this regard, there arises a need to solve the problem of wastewater treatment. The process of cyanide removal is well known and proven in an industrial scale. The presence of nonferrous metal sulfides and iron in ore concentrates leads to an increased consumption of cyanides caused by thiocyanate production. As a result, gold mining companies have to solve the problem of neutralization of discharged water both in terms of cyanide and thiocyanates. The problem is currently particularly burning at Russia’s operations as requirements for cyanide and thiocyanate contents in treated effluents are virtually commensurate. This present paper summarizes the results of research in the field of treatment of wastewater containing, along with cyanides, a significant amount of thiocyanates. Our studies have shown high efficiency of the process of wastewater oxidation by ozone. It has been shown that the ozone oxidation process runs at high rate and is accompanied by cyanide regeneration. This saves more than fifty percent on the cost of ozone production, the latter being a major economic limiting factor for the application of this technology. The ozonation technology ensures the absence of secondary contamination by reagents and treated effluent intermediates. The developed method provides the compliance with the legislation requirements on the content of cyanides and thiocyanates in wastewater. Lower cost of the process resulted from the lack of reagents, and hence, cost of their purchase and delivery to gold mining operations, and a potential for cyanide regeneration make a proposed method very attractive. Normal 0 false false false RU X-NONE X-NONE /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Обычная таблица"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin-top:0cm; mso-para-margin-right:0cm; mso-para-margin-bottom:8.0pt; mso-para-margin-left:0cm; line-height:107%; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-fareast-language:EN-US;}
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