{"title":"硬链分子的旋转半径与链长及与溶剂的相互作用有关","authors":"R. Kirste","doi":"10.1039/DF9704900051","DOIUrl":null,"url":null,"abstract":"The radius of gyration and the second osmotic virial coefficient of a model chain molecule is calculated numerically with a Monte Carlo procedure. The model is intended to resemble cellulose trinitrate (CTN). The expansion coefficients of stiff chain molecules such as CTN or DNA are near unity at high molecular weights and in good solvents.","PeriodicalId":11262,"journal":{"name":"Discussions of The Faraday Society","volume":"23 1","pages":"51-59"},"PeriodicalIF":0.0000,"publicationDate":"1970-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"13","resultStr":"{\"title\":\"Radius of gyration of stiff chain molecules as a function of the chain length and the interactions with the solvent\",\"authors\":\"R. Kirste\",\"doi\":\"10.1039/DF9704900051\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The radius of gyration and the second osmotic virial coefficient of a model chain molecule is calculated numerically with a Monte Carlo procedure. The model is intended to resemble cellulose trinitrate (CTN). The expansion coefficients of stiff chain molecules such as CTN or DNA are near unity at high molecular weights and in good solvents.\",\"PeriodicalId\":11262,\"journal\":{\"name\":\"Discussions of The Faraday Society\",\"volume\":\"23 1\",\"pages\":\"51-59\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1970-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"13\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Discussions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/DF9704900051\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Discussions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/DF9704900051","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Radius of gyration of stiff chain molecules as a function of the chain length and the interactions with the solvent
The radius of gyration and the second osmotic virial coefficient of a model chain molecule is calculated numerically with a Monte Carlo procedure. The model is intended to resemble cellulose trinitrate (CTN). The expansion coefficients of stiff chain molecules such as CTN or DNA are near unity at high molecular weights and in good solvents.
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