离子液体:有机溶剂进行有机合成的最佳替代品

K. Kumari, P. Singh, G. K. Mehrotra
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引用次数: 10

摘要

离子液体完全由离子(即阳离子和阴离子)组成,曾经是电化学家和有机化学家最感兴趣的东西。离子液体作为一种环境友好的反应介质,具有巨大的可持续化学合成潜力。自20世纪90年代末以来,迅速增加的研究工作表明,离子液体由于其用途广泛,可以在广泛的有机合成中取代传统的和有潜在危险的有机溶剂。越来越多的证据表明,离子液体的应用可以拓宽催化行为的范围。然而,近年来,除其他外,它们缺乏可测量的蒸气压或低蒸气压证明它们是有机合成的绿色溶剂,并且可以在它们中进行广泛的化学反应,如本文所述。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Ionic Liquid: Best Alternate to Organic Solvent to Carry Out Organic Synthesis
ABSTRACT Ionic liquids, being composed entirely of ions, that is, cations and anions, were once mainly of interest to electrochemists and organic chemists. Ionic liquid has prodigious potential as an environmentally benign reaction medium for sustainable chemical synthesis. Since the end of the 1990s, rapidly increasing research efforts have shown that ionic liquid can replace conventional and potentially hazardous organic solvents in a wide range of organic synthesis due to their versatile applications. There is also increasing evidence that the application of ionic liquid can broaden the scope of catalytic behavior. Recently, however, it has become apparent that, inter-alia, their lack of measurable or low vapor pressure proved them as green solvents for the organic synthesis and that a wide range of chemical reactions can be performed in them as discussed in this review.
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