BULK CHEMISTRY OF KARST SEDIMENT DEPOSITS.

Sediments are ubiquitous in karst systems and play a critical role in the fate and transport of contaminants. Sorbed contaminants may be stored on immobile sediments or rapidly dispersed on mobile sediments. Sediments may also influence remediation by either enhancing or interfering with the process. To better understand the potential effects of sediments on remediation, we conducted physical and chemical characterizations of 11 sediment samples from 7 cave and spring deposits from karst regions of Tennessee, Virginia, and West Virginia. The samples were analyzed for particle-size distribution using sieves and laser diffraction particle analysis. The sediment size fraction <2 mm (sand, silt, and clay) was analyzed for slurry pH and specific conductivity (SC) using electrodes and for bulk total carbon, organic carbon, nitrogen and sulfur on an ElementarTM Vario MAX Cube CNS. The same <2 mm fraction was subjected to a pseudo-total extraction using aqua regia with subsequent solution analysis by inductively coupled plasma-optical emission spectrometry (ICP-OES). Most of the samples were dominated by the <2 mm size fraction. Their slurry pHs ranged from 6.8 to 8.4 and their SCs ranged from 45 to 206 μS/cm with the exception of two high SC samples (726 and 8500 μS/cm). The fraction of organic carbon (Foc) in the sediments ranged from <0.1 to 2%. The sample from a saltpeter cave historically used for gunpowder production contained the highest concentrations of N and S (~3 g/kg) but lower total C than some of the spring samples. The pseudo-total extractions were analyzed for Al, Ca, Fe, Mg, and Mn. Of those elements, Mg was the most consistent across the locations (2.0-6.1 g/kg), and Ca was the most variable (1.4-52 g/kg). Given the importance of particle size and elemental concentrations in chemical reactions and remediation, more data of this type are needed to predict contaminant fate and transport and to plan successful remediation projects.