William T.A Harrison , Mark L.F Phillips , Tina M Nenoff
{"title":"(CN4H7)2·Zn3(HPO3)4，三维框架锌磷酸酯:模板-模板合作的一个例子?","authors":"William T.A Harrison , Mark L.F Phillips , Tina M Nenoff","doi":"10.1016/S1466-6049(01)00076-9","DOIUrl":null,"url":null,"abstract":"<div><p><span>The hydrothermal synthesis and single crystal structure of (CN</span><sub>4</sub>H<sub>7</sub>)<sub>2</sub>·Zn<sub>3</sub>(HPO<sub>3</sub>)<sub>4</sub> are reported. This phase is built up from a network of vertex-linked ZnO<sub>4</sub> and HPO<sub>3</sub> building units encapsulating the extra-framework animoguanidinium cations. A new type of three-dimensional network for the inorganic component of the structure arises, which contains polyhedral 4-, 6-, 8-, 12- and 16-rings. There are close (∼3.6 Å), side-on, template–template contacts similar to those seen between pairs of guanidinium cations in molecular compounds. Crystal data: (CN<sub>4</sub>H<sub>7</sub>)<sub>2</sub>·Zn<sub>3</sub>(HPO<sub>3</sub>)<sub>4</sub>, <em>M</em><sub>r</sub>=666.30, monoclinic, space group <em>P</em>2<sub>1</sub>/<em>n</em> (No. 14), <em>a</em>=10.2589 (4) Å, <em>b</em>=29.5851 (12) Å, <em>c</em>=13.7578 (5) Å, <em>β</em>=103.303 (1)°, <em>V</em>=4063.6 (5) Å<sup>3</sup>, <em>Z</em>=8, <em>T</em>=298 (2) K, <em>R</em>(<em>F</em>)=0.0399, <em>wR</em>(<em>F</em><sup>2</sup>)=0.0792.</p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 7","pages":"Pages 1033-1038"},"PeriodicalIF":0.0000,"publicationDate":"2001-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00076-9","citationCount":"42","resultStr":"{\"title\":\"(CN4H7)2·Zn3(HPO3)4, a three-dimensional framework zincophosphite: an example of template–template co-operation?\",\"authors\":\"William T.A Harrison , Mark L.F Phillips , Tina M Nenoff\",\"doi\":\"10.1016/S1466-6049(01)00076-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span>The hydrothermal synthesis and single crystal structure of (CN</span><sub>4</sub>H<sub>7</sub>)<sub>2</sub>·Zn<sub>3</sub>(HPO<sub>3</sub>)<sub>4</sub> are reported. This phase is built up from a network of vertex-linked ZnO<sub>4</sub> and HPO<sub>3</sub> building units encapsulating the extra-framework animoguanidinium cations. A new type of three-dimensional network for the inorganic component of the structure arises, which contains polyhedral 4-, 6-, 8-, 12- and 16-rings. There are close (∼3.6 Å), side-on, template–template contacts similar to those seen between pairs of guanidinium cations in molecular compounds. Crystal data: (CN<sub>4</sub>H<sub>7</sub>)<sub>2</sub>·Zn<sub>3</sub>(HPO<sub>3</sub>)<sub>4</sub>, <em>M</em><sub>r</sub>=666.30, monoclinic, space group <em>P</em>2<sub>1</sub>/<em>n</em> (No. 14), <em>a</em>=10.2589 (4) Å, <em>b</em>=29.5851 (12) Å, <em>c</em>=13.7578 (5) Å, <em>β</em>=103.303 (1)°, <em>V</em>=4063.6 (5) Å<sup>3</sup>, <em>Z</em>=8, <em>T</em>=298 (2) K, <em>R</em>(<em>F</em>)=0.0399, <em>wR</em>(<em>F</em><sup>2</sup>)=0.0792.</p></div>\",\"PeriodicalId\":100700,\"journal\":{\"name\":\"International Journal of Inorganic Materials\",\"volume\":\"3 7\",\"pages\":\"Pages 1033-1038\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00076-9\",\"citationCount\":\"42\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Inorganic Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1466604901000769\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Inorganic Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1466604901000769","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
(CN4H7)2·Zn3(HPO3)4, a three-dimensional framework zincophosphite: an example of template–template co-operation?
The hydrothermal synthesis and single crystal structure of (CN4H7)2·Zn3(HPO3)4 are reported. This phase is built up from a network of vertex-linked ZnO4 and HPO3 building units encapsulating the extra-framework animoguanidinium cations. A new type of three-dimensional network for the inorganic component of the structure arises, which contains polyhedral 4-, 6-, 8-, 12- and 16-rings. There are close (∼3.6 Å), side-on, template–template contacts similar to those seen between pairs of guanidinium cations in molecular compounds. Crystal data: (CN4H7)2·Zn3(HPO3)4, Mr=666.30, monoclinic, space group P21/n (No. 14), a=10.2589 (4) Å, b=29.5851 (12) Å, c=13.7578 (5) Å, β=103.303 (1)°, V=4063.6 (5) Å3, Z=8, T=298 (2) K, R(F)=0.0399, wR(F2)=0.0792.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
