{"title":"第一个螯合磷氮二氧配体:MoO(O2)2片段的络合","authors":"W. Thiel, Thomas Priermeier, Tassilo Bog","doi":"10.1039/C39950001871","DOIUrl":null,"url":null,"abstract":"2-Diphenylphosphinoyl-N,N-dimethylaniline is oxidized at nitrogen by a dilute solution of H2O2 in the presence of MoO(O2)2·(H2O)x; the resulting phosphorus–nitrogen dioxo-ligand forms a molybdenum oxobisperoxo complex, which is structurally characterized by single crystal X-ray diffraction.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"36 1","pages":"1871-1872"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"The first chelating phosphorus–nitrogen dioxo ligand: complexation of an MoO(O2)2 fragment\",\"authors\":\"W. Thiel, Thomas Priermeier, Tassilo Bog\",\"doi\":\"10.1039/C39950001871\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"2-Diphenylphosphinoyl-N,N-dimethylaniline is oxidized at nitrogen by a dilute solution of H2O2 in the presence of MoO(O2)2·(H2O)x; the resulting phosphorus–nitrogen dioxo-ligand forms a molybdenum oxobisperoxo complex, which is structurally characterized by single crystal X-ray diffraction.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"36 1\",\"pages\":\"1871-1872\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950001871\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001871","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
摘要
2-二苯基膦酰- n, n -二甲苯胺在MoO(O2)2·(H2O)x的存在下，被H2O2的稀溶液在氮气下氧化;所得的磷氮二氧配体形成钼氧双氧配合物，其结构通过单晶x射线衍射表征。
The first chelating phosphorus–nitrogen dioxo ligand: complexation of an MoO(O2)2 fragment
2-Diphenylphosphinoyl-N,N-dimethylaniline is oxidized at nitrogen by a dilute solution of H2O2 in the presence of MoO(O2)2·(H2O)x; the resulting phosphorus–nitrogen dioxo-ligand forms a molybdenum oxobisperoxo complex, which is structurally characterized by single crystal X-ray diffraction.
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