M.John Plater , Mark R St J. Foreman , Thomas Gelbrich , Michael B Hursthouse
{"title":"1,6-双(4-吡啶基)己烷与硝酸铜无限配位网络的合成与表征","authors":"M.John Plater , Mark R St J. Foreman , Thomas Gelbrich , Michael B Hursthouse","doi":"10.1016/S1463-0184(01)00024-7","DOIUrl":null,"url":null,"abstract":"<div><p>Crystallisation of 1,6-bis(4-pyridyl)hexane (Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>) with copper nitrate gives two different phases. Phase <strong>1</strong> of composition [Cu(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)<sub>3</sub>(NO<sub>3</sub>)<sub>2</sub>]·2[Cu(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)<sub>2</sub>(H<sub>2</sub>O)(NO<sub>3</sub>)]·2(NO<sub>3</sub><span>)·EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains </span><em>I</em> to <em>II</em> and chains <em>II</em> to <em>II</em>. In contrast phase <strong>2</strong> of composition [Cu<sub>2</sub>(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>]·(NO<sub>3</sub>)<sub>4</sub>·(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)·(EtOH)·2(H<sub>2</sub>O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent.</p></div>","PeriodicalId":10766,"journal":{"name":"Crystal Engineering","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1463-0184(01)00024-7","citationCount":"25","resultStr":"{\"title\":\"Synthesis and characterisation of infinite coordination networks with 1,6-bis(4-pyridyl)hexane and copper nitrate\",\"authors\":\"M.John Plater , Mark R St J. Foreman , Thomas Gelbrich , Michael B Hursthouse\",\"doi\":\"10.1016/S1463-0184(01)00024-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Crystallisation of 1,6-bis(4-pyridyl)hexane (Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>) with copper nitrate gives two different phases. Phase <strong>1</strong> of composition [Cu(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)<sub>3</sub>(NO<sub>3</sub>)<sub>2</sub>]·2[Cu(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)<sub>2</sub>(H<sub>2</sub>O)(NO<sub>3</sub>)]·2(NO<sub>3</sub><span>)·EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains </span><em>I</em> to <em>II</em> and chains <em>II</em> to <em>II</em>. In contrast phase <strong>2</strong> of composition [Cu<sub>2</sub>(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>]·(NO<sub>3</sub>)<sub>4</sub>·(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)·(EtOH)·2(H<sub>2</sub>O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent.</p></div>\",\"PeriodicalId\":10766,\"journal\":{\"name\":\"Crystal Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1463-0184(01)00024-7\",\"citationCount\":\"25\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystal Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1463018401000247\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1463018401000247","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and characterisation of infinite coordination networks with 1,6-bis(4-pyridyl)hexane and copper nitrate
Crystallisation of 1,6-bis(4-pyridyl)hexane (Py2C6H12) with copper nitrate gives two different phases. Phase 1 of composition [Cu(Py2C6H12)3(NO3)2]·2[Cu(Py2C6H12)2(H2O)(NO3)]·2(NO3)·EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains I to II and chains II to II. In contrast phase 2 of composition [Cu2(Py2C6H12)4(H2O)2]·(NO3)4·(Py2C6H12)·(EtOH)·2(H2O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent.
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